Experimental and numerical assessment of grain boundary energies in polycrystalline uranium dioxide |
| |
Affiliation: | 1. CEA, IRESN?DEC, Cadarache, 13108 St Paul Lez Durance, France;2. University Grenoble Alpes, CEA, IRIG-PHELIQS, F-38000 Grenoble, France;3. Univ. Grenoble Alpes, CNRS, Grenoble INP, Institut Néel, 38000 Grenoble, France;1. Key Laboratory of Road Construction Technology and Equipment, MOE, Chang’an University, Xi’an, 710064, China;2. Key Laboratory of Pressure Systems and Safety, Ministry of Education, East China University of Science and Technology, Shanghai, 200237, China;1. CEA, DEN, DEC, SESC, LSC bat 151 Centre de Cadarache, 13108 Saint Paul Lez Durance, France;2. EDF R&D, Site des Renardières, Dpt MMC, Avenue des Renardières, 77818 Moret sur Loing, France;1. CEA, DEN, DEC, Cadarache, 13108, Saint-Paul-Lez-Durance, France;2. Laboratoire D’Etude des Microstructures et de Mécanique des Matériaux (LEM3), UMR CNRS 7239, Université de Lorraine, 57045, Metz Cedex 1, France |
| |
Abstract: | Uranium dioxide ceramics are widely used as nuclear fuels. Thus, it is important to understand the role of the grain boundaries (GBs) which decisively govern the properties of these polycrystalline materials and subsequently determine their performances. Here, we report a coupled numerical - experimental approach enabling to assess GB energies. Firstly, GB formation energies (γgb) were computed for 34 symmetric tilt GBs in UO2 with molecular dynamics simulations at 1700 K. The surface energies (γS) relative to the respective planes of these GBs were calculated as well. The Herring relation was then used to assess the dihedral angles Ψ of the corresponding GB grooves. Secondly, a UO2 ceramic sample was annealed at 1673 K to obtain GB grooves. The CSL GBs of interest were identified by EBSD and their Ψ angles determined by AFM. Computed and measured Ψ values were found to be very close. |
| |
Keywords: | Uranium dioxide Grain boundaries Groove Thermal grooving theory Grain boundary energy Surface energy CRG potential |
本文献已被 ScienceDirect 等数据库收录! |
|