| 1,2-二氯乙烷光催化氧化合成氯乙酸的研究 |
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| 引用本文： | 陈雨生,金鑫丽.1,2-二氯乙烷光催化氧化合成氯乙酸的研究[J].浙江工业大学学报,1991(1). |
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| 作者姓名： | 陈雨生 金鑫丽 |
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| 作者单位： | 浙江工学院化学工程系
(陈雨生)，浙江工学院化学工程系(金鑫丽) |
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| 摘 要： | 本文研究了以1,2—二氯乙烷为原料通过光催化氧化合成氯乙酸的新途径,以及有关反应条件对氯乙酸生成收率的影响;同时提出了可能的反应机理.由于反应原料价格便宜,生产方法简单,条件温和,所以此法是一种有意义的氯乙酸合成方法.
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| 关 键 词： | 氯乙酸 1 2-二氯乙烷 氧气 氯气 光催化氧化反应 |
An Explorative Study on Synthesis of Monochloroacetic from 1,2-Dichloroethance by Photooxidation |
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| Chen Yusheng Jin Xnli.An Explorative Study on Synthesis of Monochloroacetic from 1,2-Dichloroethance by Photooxidation[J].Journal of Zhejiang University of Technology,1991(1). |
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| Authors: | Chen Yusheng Jin Xnli |
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| Affiliation: | Department of Chemical Engineering |
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| Abstract: | An experimental and theoretic study has carried out to a new method of synthesis monochloroacetic acid 1,1,2-trichloroethane fron 1,2-dichloroethane. The influence of the various reaction conditions on the mole yield of monochloroacetic acid has been di scussed.An interpretation of the mechanism of pho-tooxidation is proposed in the article. The economic importance of the new method needs no comment because the method and reaction conditions are simple. The raw material is cheap. |
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| Keywords: | Monochloroacetic acid 1 2-Dichloroethan Oxygen gas Chlorine gas Photooxidation |
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