| 长寿命的含氟自由基研究 |
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| 引用本文： | 赵祥臻.长寿命的含氟自由基研究[J].上海工程技术大学学报,1996,10(2):1-8. |
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| 作者姓名： | 赵祥臻 |
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| 作者单位： | 中国科学院上海有机化学研究所!上海200032 |
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| 摘 要： | 本文以大量实验数据报导关于辐照有机氟化合物和氟聚合物内含氟有机自由基在室温长时间稳定性的观察结果及其引发接枝反应和引发单体聚合及共聚合的实验结果，显示含氟有机自由基是一类长寿命的活性自由基。并讨论了含氟有机自由基的良好室温稳定性的机理。
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| 关 键 词： | 活性 自由基 有机氟化合物 聚合物 辐射（照） |
A RESEARCH ON LONG LIVED ACTIVE RADICALS-FLUORINE-CONTAINING ORGANIC RADICALS |
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| Zhao Xangzhen.A RESEARCH ON LONG LIVED ACTIVE RADICALS-FLUORINE-CONTAINING ORGANIC RADICALS[J].Journal of Shanghai University of Engineering Science,1996,10(2):1-8. |
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| Authors: | Zhao Xangzhen |
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| Affiliation: | Zhao Xangzhen |
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| Abstract: | A lot of experimental data of stability of fluorine-containing organic radicals at room temperature contained in irradiated fluoro-organic compounds or fluoropolymers were observed with ESR for a long time. With the chemical activity, such radicals can initiate the graft reaction of fluoropolymers and the polymerization and copolymerization of some vinyl monomers. This paper also discussed the mechanism of excellent stability of fluorine-containing organic radicals at room temperature. |
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| Keywords: | Activity Free radicals Organohalogen compounds Polymers Radiation |
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