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La/金红石相TiO2的光催化性能
引用本文:宋绵新,边亮,马丽阳,周天亮,习永广,戴清清.La/金红石相TiO2的光催化性能[J].四川建材学院学报,2010(1):1-5,44.
作者姓名:宋绵新  边亮  马丽阳  周天亮  习永广  戴清清
作者单位:[1]西南科技大学材料科学与工程学院先进建筑材料四川省重点实验室,四川绵阳621010 [2]中国工程物理研究院化工材料研究所,四川绵阳621009 [3]北京科技大学,北京100018 [4]上海东海海洋工程勘察设计研究院,上海200137
基金项目:基金项目:四川省教育厅重点项目(2006A099);国防基础研究项目(A3120080126).
摘    要:以钛酸丁酯和氧化镧为原料,通过一步法合成金红石相TiO2和La/金红石相TiO2。利用XRD、比表面积、DRS、Zeta电位等表征La/金红石相TiO2的光催化活性性能。结果表明,质量分数1.00%的La/,金红石相TiO2光催化活性最优。以甲基红、甲基橙和亚基甲蓝为降解目标的光催化,其反应动力学参数与表征结果吻合。

关 键 词:  金红石  TiO2  光催化活性  反应动力学

The Band Gap Calculation of Energy Band of Anatase, Rutile and Brookite TiO2
Authors:SONG Mian-xin  BIAN Liang  MA Li-yang  ZHOU Tian-iiang  XI Yong-guang  DAI Qing-qing
Affiliation:1. Key Laboratory for Advanced Building Materials of Sichuan Province, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China; 2. China Academy of Engineering Physics, Institute of Chemical Materials, Mianyang 621009, Sichuan, China; 3. University of Science and Technology Beijing, Beijing 100018, China; 4. Shanghai East Wea Marine Engineering Survey and Design Institute, Shanghai 200137, China )
Abstract:The futile TiO2 and La/rutile TiO2 were synthesized by one-step method. The photocatalytic activity of La /rutile TiO2 were characterized by XRD, specific surface area, DRS, Zate potential, et al. The result shows that the photocatalytic activity of 1.00% La/rutile TiO2 is the best. Besides Methyl orange reaction and Methylene blue trihydrate are degradation of the target. By kinetics parameters of photocatalyzing Methyl orange reaction, the kinetics parameters are similar with the results of characterization such as k and t0.5.
Keywords:La  Rrutile  TiO2  Photocatalytic activity  Kinetics
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