Carbon Solubility and Mass Action Concentrations of Fe-Cr-C Melts |
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作者单位: | Metallurgy School,University of Science and Technology Beijing,Beijing 100083,China |
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摘 要: |
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Carbon Solubility and Mass Action Concentrations of Fe-Cr-C Melts |
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Authors: | Jian Zhang |
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Abstract: | An empirical equation of carbon solubility in Fe-Cr-C melts is regressed based on the experimental data from references. Acalculating model of mass action concentrations for these melts is formulated on the basis of the coexistence theory of metaIlic melts in-volving compound formation, the phase diagram of Cr-C system as well as thermodynamic data of Fe-Cr-C melts. According to the mod-el, the standard Gibbs free energies of formation of CrC and Cr3C2 are obtained. Satisfactory agreement between the calculated and me-asured values shows that the model can reflect the structural characteristics of Fe-Cr-C melts. |
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Keywords: | activity coexistence theory mass action concentration saturated state |
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