| 菜籽油基单甘油酯马来酸单酯与苯乙烯共聚条件的探讨 |
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| 引用本文： | 高冠斌,胡洋,蒋雷,刘伟,刘晓洪.菜籽油基单甘油酯马来酸单酯与苯乙烯共聚条件的探讨[J].武汉纺织工学院学报,2009(4). |
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| 作者姓名： | 高冠斌 胡洋 蒋雷 刘伟 刘晓洪 |
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| 作者单位： | 武汉科技学院纺织与材料学院 |
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| 基金项目： | 武汉科技学院基金项目(20063115) |
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| 摘 要： | 随着石油资源的日益枯竭和环境污染问题的日趋严重,植物油作为一种可再生的绿色生物基资源,以其产量巨大、可储存和碳循环等优点引起全球的广泛关注。本课题采用菜籽油在一定条件下先后与甘油(glycerin)和马来酸酐(MA)反应生成菜籽油基单甘油酯马来酸单酯(ROMG-MA),然后与苯乙烯发生共聚合反应,转化为热固性树脂。讨论分析了各个反应条件对产物总转化率的影响,得出ROMG-MA与苯乙烯共聚合反应的适宜条件为:ROMG-MA质量分数50%、BPO的质量分数5%、苯乙烯的质量分数45%、反应温度90℃,反应时间1.0h。
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| 关 键 词： | 菜籽油 菜籽油甘油单酸酯 菜籽油基单甘油酯马来酸单酯 热固性树脂 |
Research on the Conditions of Copolymerization of ROMG-MA and Styrene |
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| Authors: | GAO Guan-bin; HU Yang; JIANG Lei; LIU Wei; LIU Xiao-hong |
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| Affiliation: | GAO Guan-bin; HU Yang; JIANG Lei; LIU Wei; LIU Xiao-hong(College of Textile and Material; Wuhan Universitry of Science and Engineering; Wuhan Hubei; 430073; China); |
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| Abstract: | With the increasing depletion of oil resources and worsening environmental pollution,plant oil as a green renewable bio-based resources,with its huge output,can be stored and the carbon cycle,etc.Which caused widespread concern around the world.In this paper,rapeseed oil met with glycerol(glycerin) and maleic anhydride(MA) to make the rapeseed oil-based monoglyceride maleate monoester(ROMG-MA) on the conditions,and then corporated with the styrene into a thermosetting resin.By discussing various reaction co... |
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| Keywords: | rape oil rape oil monoglyceride rape oil monoglyceride maleates thermosetting resin |
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