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巯基中空纤维亲和膜Hg2+动态等温吸附方程的计算机模拟
引用本文:黄橡丽,王兵.巯基中空纤维亲和膜Hg2+动态等温吸附方程的计算机模拟[J].天津工业大学学报,2006,25(2):61-64.
作者姓名:黄橡丽  王兵
作者单位:1. 天津商学院,信息工程学院,天津,300134
2. 天津工业大学,材料科学与化学工程学院,天津,300160
基金项目:教育部科学技术研究项目
摘    要:在测定巯基中空纤维亲和膜对Hg ^2+动态等温吸附方程的基础上,利用C++语言编程,按Langmuir、Lang- muir-Freundlich和扩展的Langmuir 3个模型对吸附Hg ^2+实验数据进行拟合,分别检验了实验数据的拟合程度.这3个模型对实验数据都拟合较好;相对其它两个模型,扩展Langmuir模型提供了最好的拟合,从而推断出巯基中空纤维亲和膜对Hg ^2+的动态等温吸附是非完全的单分子层吸附.

关 键 词:巯基中空纤维亲和膜  等温吸附  模型模拟  C  语言
文章编号:1671-024X(2006)02-0061-04
收稿时间:2005-12-24
修稿时间:2005年12月24

Computer simulation of dynamic isothermal adsorption of hollow fiber affinity membrane modified with mercapto for Hg2+
HUANG Xiang-li,WANG Bing.Computer simulation of dynamic isothermal adsorption of hollow fiber affinity membrane modified with mercapto for Hg2+[J].Journal of Tianjin Polytechnic University,2006,25(2):61-64.
Authors:HUANG Xiang-li  WANG Bing
Affiliation:1. School of Information Engineering, Tianjin Commercial University, Tianjin 300134, China; 2. School of Material Science and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300160, China
Abstract:On the basis of dynamic isothermal adsorption, the three models for Langmuir, Langmuir-Freundlich and Ex-pended-Langmuir are used to fit the experimental data of Hg2 + adsorbed by the hollow fiber affinity membrane modified with mercapto, and the fitting degree of the three models to the experimental data is investigated by Language C + + . The results show that the three models can fit to the experimental data. Compare with other models, the Expended-Langmuir model gives the best fitting. Then it can be inferred that the dynamic isothermal adsorption of the hollow fiber affinity membrane modified with mercapto for Hg2 + is not complete monolayer adsorption.
Keywords:hollow fiber affinity membrane modified with mercapto  isotherms adsorption  models simulation  Language C+ +
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