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PSAF-PDMDAAC复合絮凝剂的制备与性能
引用本文:张锐,付颖寰,宋宇,王永为,于春玲,董晓丽,薛文平.PSAF-PDMDAAC复合絮凝剂的制备与性能[J].大连工业大学学报,2012,31(3):195-198.
作者姓名:张锐  付颖寰  宋宇  王永为  于春玲  董晓丽  薛文平
作者单位:大连工业大学轻工与化学工程学院,辽宁大连,116034
基金项目:国家自然科学基金资助项目,辽宁省科学技术基金
摘    要:以聚二甲基二烯丙基氯化铵(PDMDAAC)为有机改性剂,制备了聚二甲基二烯丙基氯化铵(PDMDAAC)-聚硅酸铝铁(PSAF)复合絮凝剂,考察了复合pH、物料配比、温度及时间等因素对PDMDAAC-PSAF絮凝性能的影响。研究发现,PDMDAAC-PSAF复合絮凝剂的最佳制备条件为:复合pH为10,m(膨润土)∶m(PDMDAAC)为200∶1,温度为60℃,反应时间为1h。此条件下获得的复合絮凝剂(质量分数为8%),在投加量为1.5%(絮凝剂与模拟染料废水体积比)时,对活性艳蓝染料模拟废水脱色率达87.7%。相比较PSAF絮凝剂(脱色率77.1%),PDMDAAC-PSAF复合絮凝剂显示出更好的絮凝脱色效果和应用前景。

关 键 词:聚硅酸铝铁  聚二甲基二烯丙基氯化铵  膨润土  复合絮凝剂

Synthesis and properties of PSAF-PDMDAAC composite flocculants
ZHANG Rui , FU Ying-huan , SONG Yu , WANG Yong-wei , YU Chun-ling , DONG Xiao-li , XUE Wen-ping.Synthesis and properties of PSAF-PDMDAAC composite flocculants[J].Journal of Dalian Dalian Polytechnic University,2012,31(3):195-198.
Authors:ZHANG Rui  FU Ying-huan  SONG Yu  WANG Yong-wei  YU Chun-ling  DONG Xiao-li  XUE Wen-ping
Affiliation:(School of Light Industry and Chemical Engineering,Dalian Polytechnic University,Dalian 116034,China)
Abstract:PDMDAAC was prepared as organic modifier of PSAF.The inorganic-organic composite flocculants PSAF-PDMDAAC were prepared for wastewater treatment.PSAF-PDMDAAC composite flocculant was studied in optimum preparation conditions for the composite pH,compound ratio,composite temperature,compound time,compound dosage,and so on.The optimum preparation is that the composite pH 10,m(bentonite)∶m(PDMDAAC)=200∶1,composite temperature is 60 ℃,compound time is 1 h.When the dosage was 1.5%(volume ratio of flocculant and water),removal of reactive blue dye wastewater rate was 87.7%.
Keywords:PSAF  PDMDAAC  bentonite  composite flocculant
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