| 三嗪环桥联双卟啉的合成和表征 |
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| 引用本文： | 安庆大,龚雯,杨启发,孙洪莎,郑国爽,王海澍.三嗪环桥联双卟啉的合成和表征[J].大连工业大学学报,2010,29(1). |
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| 作者姓名： | 安庆大 龚雯 杨启发 孙洪莎 郑国爽 王海澍 |
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| 作者单位： | 大连工业大学,化工与材料学院,辽宁,大连,116034 |
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| 基金项目： | 辽宁省科学技术基金，辽宁省教育厅科学研究计划 |
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| 摘 要： | 为了构建新型桥联卟啉化合物,以三聚氯氰分别和5-(4-羟基苯基)-10,15,20-三苯基卟啉(Ⅰ)、5-(4-羟基苯基)-10,15,20-三苯基铜卟啉(Ⅱ)和5-(4-羟基苯基)-10,15,20-三苯基钴卟啉(Ⅲ)为原料,合成了单取代的三嗪环卟啉化合物(Ⅳ,Ⅴ),进而合成了两种新型含有三嗪环的桥联卟啉化合物(Ⅵ,Ⅶ)。采用紫外-可见光谱(UV-Vis)、红外光谱(IR)等对中间体和目标化合物的结构进行了表征,对主要的谱带进行了经验归属,初步确定了合成产物的结构。
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| 关 键 词： | 双卟啉化合物 三聚氯氰 合成 表征 |
Synthesis and characterization of triazine ring-bridged porphyrin dimmers |
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| AN Qing-da,GONG Wen,YANG Qi-fa,SUN Hong-sha,ZHENG Guo-shuang,WANG Hai-shu.Synthesis and characterization of triazine ring-bridged porphyrin dimmers[J].Journal of Dalian Dalian Polytechnic University,2010,29(1). |
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| Authors: | AN Qing-da GONG Wen YANG Qi-fa SUN Hong-sha ZHENG Guo-shuang WANG Hai-shu |
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| Abstract: | In order to construct a new bridged porphyrin compound,a novel covalently linked triazine-porphyrin complexes(Ⅵ,Ⅶ) were synthesized by cyanuric chloride with 5-(4-hydroxyphenyl)-10,15,20-triphenyl porphyrin(Ⅰ) and its copper,cobalt derivatives(Ⅱ,Ⅲ) respectively.The two new triazine-porphyrin compounds were characterized by UV-Vis,IR,which are predicted to have good electrical properties. |
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| Keywords: | porphyrin dimmers cyanuric chloride synthesis characterization |
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