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油溶性油酸镍对辽河稠油的降黏作用
引用本文:陈尔跃,刘永建,梁敏,邬洪源,韩成利.油溶性油酸镍对辽河稠油的降黏作用[J].大庆石油学院学报,2010,34(6).
作者姓名:陈尔跃  刘永建  梁敏  邬洪源  韩成利
作者单位:1. 齐齐哈尔大学,化学与化工学院,黑龙江,齐齐哈尔,161006
2. 东北石油大学,石油工程学院,黑龙江,大庆,163318
基金项目:黑龙江省教育厅科学技术研究项目(11531408); 教育部高等学校博士学科点专项科研基金项目(200802200001)
摘    要:为避免在井下没有搅拌装置的条件下,水溶性催化剂在水热裂解反应中难以与稠油充分接触,制备油溶性的油酸镍作为水热裂解反应的催化剂.结果表明:油溶性催化剂优于水溶性催化剂;辽河稠油、30%(质量分数)地层水和0.4%(质量分数)油酸镍在200℃反应24 h后稠油降黏率可达63.1%;0.1%(质量分数)甲苯与催化剂协同进行水热裂解反应,稠油降黏率可达81.3%;稠油组成发生重组分减少,轻组分增加变化.

关 键 词:油酸镍  甲苯  水热裂解  稠油  降黏  辽河稠油

A study on the viscosity reduction of Liaohe heavy oil by oil-soluble nickel oleate
CHEN Er-yue,LIU Yong-jian,LIANG Min,WU Hong-yuan,HAN Cheng-li.A study on the viscosity reduction of Liaohe heavy oil by oil-soluble nickel oleate[J].Journal of Daqing Petroleum Institute,2010,34(6).
Authors:CHEN Er-yue  LIU Yong-jian  LIANG Min  WU Hong-yuan  HAN Cheng-li
Affiliation:CHEN Er-yue1,LIU Yong-jian2,LIANG Min1,WU Hong-yuan1,HAN Cheng-li1(1.Chemistry and Chemical Engineering College,Qiqihaer University,Qiqihaer,Heilongjiang 161006,China,2.Petroleum Engineering College,Northeast Petroleum University,Daqing,Heilongjiang 163318,China)
Abstract:The heavy oil and the catalyst cannot be fully contacted without stirring in down-hole.The oil-soluble catalyst is prepared in order to resolve the surface problem.The oil-soluble catalyst is better than water-soluble catalyst without stirring.The results show that the viscosity reduction rate can reach 63.1% after the quathermolysis reaction using heavy oil 30% water and 0.4% oil-soluble nickel oleate as catalyst at 200 ℃,24 hr and the viscosity reduction rate can reach 81.3% with the synergistic effect between the catalyst and 0.1 toluene.The components of heavy oil are changed in which the light components increased and heavy components decreased.
Keywords:nickel oleate  toluene  aquathermolysis  heavy oil  viscosity reduction  Liaohe heavy oil  
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