| 聚邻乙氧基苯胺的化学氧化法合成及表征 |
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| 引用本文： | 张银玲,黄英,吴海伟,吴燕飞,牛磊.聚邻乙氧基苯胺的化学氧化法合成及表征[J].西北工业大学学报,2011,29(6):877-882. |
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| 作者姓名： | 张银玲 黄英 吴海伟 吴燕飞 牛磊 |
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| 作者单位： | 西北工业大学应用化学系,陕西西安,710072 |
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| 基金项目： | 西北工业大学2011年度研究生创业种子基金(Z2011021)资助 |
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| 摘 要： | 采用化学氧化法、以盐酸为掺杂剂,合成了一种国内目前尚未深入研究的新型导电高聚物——聚苯胺衍生物聚邻乙氧基苯胺(POEA).采用X-射线衍射(XRD)、傅里叶转换红外光谱(FTIR)、固体核磁共振波谱(13C-NMR)、扫描电镜(SEM)、凝胶渗透色谱(GPC)、紫外可见吸收光谱(UV-Vis)、四探针法、矢量网络分析仪...
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| 关 键 词： | POEA 合成 化学氧化法 |
Synthesis by Chemical Oxidation and Characterization of Poly(o-ethoxyaniline)(POEA) |
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| Zhang Yinling
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Huang Ying
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Wu Haiwei
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Wu Yanfei
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Niu Lei.Synthesis by Chemical Oxidation and Characterization of Poly(o-ethoxyaniline)(POEA)[J].Journal of Northwestern Polytechnical University,2011,29(6):877-882. |
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| Authors: | Zhang Yinling Huang Ying Wu Haiwei Wu Yanfei Niu Lei |
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| Affiliation: | (Department of Applied Chemistry,Northwestern Polytechnical University,Xi′an 710072,China) |
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| Abstract: | POEA is a new type of conductive polymer.To our knowledge,Chinese reseachers have not yet carried out a deep research on this issue.In this paper,we synthesized POEA by chemical oxidation,using hydrochloric acid as dopant.The crystalline phase,microstructure,surface appearance,molecular weight and its distribution,oxidation-reduction degree,conductivity and thermostability of POEA were characterized.X-Ray diffraction(XRD) spectrogram suggested that POEA was amorphous.Fourier transform infrared(FTIR) spectro... |
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| Keywords: | amorphous materials analysis characterization conductive materials differential scanning calorimetry doping(additives) Fourier transform infrared spectroscopy frequencies gel permeation chromatography magnetic resonance measurements microstructure oxidation polymers spectroscopy stability synthesis(chemical) thermogravimetric analysis X-ray diffraction poly(o-ethoxyaniline)(POEA) |
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