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采用微生物覆铜板浸出液中铁离子制备 Fe2O3/石墨烯纳米复合材料的研究
引用本文:张迎春,汪明珠,于伟.采用微生物覆铜板浸出液中铁离子制备 Fe2O3/石墨烯纳米复合材料的研究[J].上海第二工业大学学报,2019(1):23-27.
作者姓名:张迎春  汪明珠  于伟
作者单位:上海第二工业大学环境与材料工程学院
基金项目:上海第二工业大学研究生项目基金(EGD17YJ0010) 资助
摘    要:针对微生物法覆铜板浸出液中的金属铁离子进行资源化处理,提高覆铜板浸出液的附加值。以水热法处理得到的铁离子溶液为原料,制备八面体和球形的Fe_2O_3/石墨烯复合材料,并将其作为锂离子电池负极材料,组装成扣式电池。结果显示:八面体形貌的Fe_2O_3/石墨烯复合材料的比容量高于球形的,其在100 mA/g电流下循环,首次放电和充电比容量分别高达1 343和970 mAh/g,在47次循环后,其放电及充电比容量分别为769和740 mAh/g。

关 键 词:电子废弃物    覆铜板    Fe2O3/石墨烯复合材料

Research on Preparing Fe2O3/Graphene Composites by Iron Ions in the Leaching Solution of Copper Clad by Microbial Technology
ZHANG Ying-chun,WANG Ming-zhu and YU Wei.Research on Preparing Fe2O3/Graphene Composites by Iron Ions in the Leaching Solution of Copper Clad by Microbial Technology[J].Journal of Shanghai Second Polytechnic University,2019(1):23-27.
Authors:ZHANG Ying-chun  WANG Ming-zhu and YU Wei
Affiliation:School of Environmental and Materials Engineering, Shanghai Polytechnic University, Shanghai 201209, China,School of Environmental and Materials Engineering, Shanghai Polytechnic University, Shanghai 201209, China and School of Environmental and Materials Engineering, Shanghai Polytechnic University, Shanghai 201209, China
Abstract:The metal iron ions in the leaching solution of copper clad by microbiological method were recovered and the added value of the leaching solution of copper clad was improved. The octahedral and spherical Fe2O3/graphene composites were prepared by using the iron ions obtained by hydrothermal method and assembled as a negative electrode for lithium ion battery. The results show that the specific volumes of Fe2O3/graphene composites with octahedral morphology are higher than that of spherical, and the octahedral Fe2O3/graphene composites are circulated at 100 mA/g, and the first discharge and charge specific volumes are as high as 1 343 and 970 mAh/g, after 47 cycles, the discharge and charge specific volumes are 769 and 740 mAh/g, respectively.
Keywords:electronic waste  copper clad  Fe2O3/graphene composites
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