高性能多孔Fe/N共掺杂碳纳米管电催化剂研究 |
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引用本文: | 吴睿,刘雄雄,陈俊松.高性能多孔Fe/N共掺杂碳纳米管电催化剂研究[J].电子科技大学学报(自然科学版),2019,48(5):682-689. |
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作者姓名: | 吴睿 刘雄雄 陈俊松 |
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作者单位: | 电子科技大学材料与能源学院 成都 611731;电子科技大学应用化学中心 成都 611731;电子科技大学材料与能源学院 成都 611731;电子科技大学应用化学中心 成都 611731;电子科技大学材料与能源学院 成都 611731;电子科技大学应用化学中心 成都 611731 |
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基金项目: | National Key Research and Development Program2018YFB1502503 |
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摘 要: | 开发高性能、低成本的氧还原催化剂是降低燃料电池成本的关键之一。过渡金属-氮-碳材料具有催化活性高、成本低、环境友好等优点,被认为具有广阔的应用前景。该文提出了一种简单的聚多巴胺改性碳纳米管的方法,在碳纳米管(CNTs)表面包覆聚多巴胺(PDA),通过高温裂解CNTs@PDA和FeCl3复合物制备多孔CNTs@Fe/N/C电催化剂。用TEM、BET、Raman和XPS对制备的催化剂的形貌和组成进行了表征。电化学结果表明,CNTs@40% Fe/N/C催化剂的半波电位高达0.881 V,接近于商业化Pt/C催化剂。此外,CNTs@40% Fe/N/C催化剂亦具备优异的抗甲醇干扰性及稳定性,是一种有良好实际应用前景的燃料电池非贵金属氧还原电催化剂。
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关 键 词: | 碳纳米管 电催化剂 Fe/N/C 氧还原反应 聚多巴胺 |
收稿时间: | 2019-07-10 |
Porous Fe/N-doped Carbon Layers Wrapped CNTs Electrocatalysts for Superior Oxygen Reduction Reaction |
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Affiliation: | 1.School of Materials and Energy, University of Electronic Science and Technology of China Chengdu 6117312.Center for Applied Chemistry, University of Electronic Science and Technology of China Chengdu 611731 |
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Abstract: | Developing high performance, low-cost oxygen reduction electrocatalysts is the key to reduce the cost of fuel cells. The transition metal-nitrogen-carbon materials have been highlighted as promising candidates owing to their high catalytic activity, low cost and environmental friendliness. Herein, we report a facile polydopamine modification approach to prepare porous CNTs@Fe/N/C elecrtocatalysts via pyrolysis of the CNTs@PDA and FeCl3 composites. The morphology and composition of these as-prepared catalysts were characterized by TEM, BET, Raman and XPS. The electrochemical results show that the half-wave potential of the CNTs@40% Fe/N/C catalyst is as high as 0.881 V, which is close to that of commercial Pt/C catalyst. Moreover, the CNTs@40% Fe/N/C also showed superior durability and resistance to the methanol crossover. |
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