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Thermodynamic calculation on the smelting slag of direct recycling of electric arc furnace stainless steelmaking dust
作者姓名:PENG  Bing
作者单位:SchoolofMetallurgicalScienceandEngineeringCentralSouthUniversity,SchoolofMetallurgicalScienceandEngineeringCentralSouthUniversity,DepartmentofMetallurgicalEngineeringMcGillUniversity,DepartmentofMetallurgicalEngineeringMcGillUniversity,SchoolofMetallurgicalScienceandEngineeringCentralSouthUniversity,SchoolofMetallurgicalScienceandEngineeringCentralSouthUniversity,SchoolofMetallurgicalScienceandEngineeringCentralSouthUniversity Changsha410083,China,DepartmentofMetallurgicalEngineering,McGillUniversity,Montreal,H3A2B2,Canada,Changsha410083,China,Montreal,H3A2B2,Canada,Montreal,H3A2B2,Canada,Changsha410083,China,Changsha410083,China,Changsha410083,China
基金项目:TheNationalNaturalScienceFoundationofChina(No .5 0 2 740 73),TheNaturalSciencesandEnginee ringResearchCouncilofCanada(Metallurgy 2 0 0 3 )
摘    要:1 INTRODUCTIONElectricarcfurnace (EAF)dusthasbeenclassifiedasahazardouswasteduetoitshighcontentofsomeheavymetalsleachabilitiessuchaszinc ,lead ,cadmiumandchromium ,soithasbeenbannedfromlandfillsinmanycoun tries .Anestimated 1 % 2 %massfractionofthescrapcharged…

收稿时间:2 November 2001

Thermodynamic calculation on the smelting slag of direct recycling of electric arc furnace stainless steelmaking dust
Peng Bing , Peng Ji , Janusz A. Kozinski, Jonathan Lobel , Chai Li-yuan , Zhang Chuan-fu and Chen Wei-liang.Thermodynamic calculation on the smelting slag of direct recycling of electric arc furnace stainless steelmaking dust[J].Journal of Central South University of Technology,2003,10(1):20-26.
Authors:Peng Bing  Peng Ji  Janusz A Kozinski  Jonathan Lobel  Chai Li-yuan  Zhang Chuan-fu and Chen Wei-liang
Affiliation:(1) School of Metallurgical Science and Engineering, Central South University, 410083 Changsha, China;(2) Department of Metallurgical Engineering, McGill University, H3A 2B2 Montreal, Canada
Abstract:Thermodynamic calculation on the smelting slag of direct recycling of electric arc furnace stainless steelmaking dust was presented. An induction furnace was used to simulate electric arc furnace smelting to recover the metals from the dust. The elements of iron, chromium and nickel in the ingot and the components of metal oxides in the slag were analyzed. The thermodynamic model for FeO-Cr2O3-MgO-SiO2 slag was set up and the active concentrations of substances in the slag at 1 550 °C were determined by thermodynamic calculation according to the experimental data. The results show that the apparent equilibrium constant and quantitative distribution of chromium between slag and steel are unstable and affected by the mass ratios of pellets to start iron and metal reducing agent to the pellets. In order to get satisfactory chromium recovery from the direct recycling of electric arc furnace stainless steelmaking dust, it is important to ensure the mass ratio of pellets to the steel below 0.20 and the mass ratio of metal reducing agent to pellets over 0.18 in practical smelting runs. Foundation item: The National Natural Science Foundation of China(No. 50274073); The Natural Sciences and Engineering Research Council of Canada (Metallurgy, 2003) Biography of the first author: PENG Bing, professor of Central South University, visiting professor of McGill University, Ph. D in metallurgical science and engineering, born in 1956, majoring in waste treatment and recycling in metallurgical processes.
Keywords:thermodynamic calculation  stainless steelmaking dust  reduction  recycling
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