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Flotation de-silicating from diasporic-bauxite with cetyl trimethylammonium bromide
作者姓名:WANG  Yu-hua
作者单位:School of Resources Processing and Bioengineering,School of Resources Processing and Bioengineering,School of Resources Processing and Bioengineering Central South University,Changsha 410083,China,Central South University,Changsha 410083,China,Central South University,Changsha 410083,China
基金项目:Project(G19990 6 4 90 1)supportedbytheNationalKeyFundamentalResearchandDevelopmentProgramofChina
摘    要:1 INTRODUCTIONTheZetapotentialsofkaolinite ,illiteandchlo riteweremeasuredforthecoalflotation ,allthesethreeclaymineralswerenegativelychargedinthepHrangeof 2 .5 11.0 1] .Theadsorptionofsodiumdode cylsulfateanddodecyltrimethylammoniumchlorideontokaolinitewasstudiedintheabsenceandpresenceofsodiumhexametaphosphate .Itwasfoundthatthepresenceofthelongchainphosphatedecreasedad sorptionoftheanionicsurfactantbutincreasedthead sorptionofthecationicsurfactant2 ] .Acommercialmonoetheramineandac…

收稿时间:29 April 2003
修稿时间:26 June 2003

Flotation de-silicating from diasporic-bauxite with cetyl trimethylammonium bromide
Wang Yu-hua , Hu Yue-hua and Liu Xiao-wen.Flotation de-silicating from diasporic-bauxite with cetyl trimethylammonium bromide[J].Journal of Central South University of Technology,2003,10(4):324-328.
Authors:Wang Yu-hua  Hu Yue-hua and Liu Xiao-wen
Affiliation:(1) School of Resources Processing and Bioengineering, Central South University, 410083 Changsha, China
Abstract:Using cetyl trimethylammonium bromide (CTAB) as collector, the flotation de-silicating from diasporicbauxite was investigated. And the Zeta potentials and contact-angles of silicate minerals and diaspore were also studied. The results show that in the presence of 2×10−4 mol·L−1CTAB, the surface charges of pyrophyllite, kaolinite and illite become more positive, and the contact angles of these three silicates also increase evidently in the pH range of 2–8, but the Zeta potentials and contact angles of diaspore change little. So, the floatability of the four minerals is in the following order: pyrophyllite>kaolinite∼illite>diaspore. The open-circuit flotation results also show that a bauxite concentrate with m(Al2O3)/m(SiO2) over 9.3 and Al2O3 recovery over 76% can be obtained from diasporic-bauxite ore. The result of XRD of the bauxite concentrate shows that pyrophyllite is easier to be removed from diasporic-bauxite than illite and kaolinite due to its better floatability. Foundation item: Project (G1999064901) supported by the National Key Fundamental Research and Development Program of China
Keywords:aluminum-silicate  bauxite  reverse flotation  cetyl trimethylammonium bromide
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