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Purification process of coal-based coke powder as anode for Li-ion batteries
引用本文:杨娟,马路路,周向阳.Purification process of coal-based coke powder as anode for Li-ion batteries[J].中南工业大学学报(英文版),2014(3):857-861.
作者姓名:杨娟  马路路  周向阳
基金项目:Projects(51274240, 51204209) supported by the National Natural Science Foundation of China; Project(2012M521545) supported by the National Postdoctoral Science Foundation of China
摘    要:A process of purification of coal-based coke powder as anode the treatment of coke powder with dilute hydrofluoric acid solution, for Li-ion batteries was attempted. The process started with followed by united-acid-leaching using sulfuric acid and hydrochloric acid. The effects of altering the hydrofluoric acid addition, hydrofluoric acid concentration, contact time, temperature and acid type were investigated. A minimum ash content of 0.35% was obtained when proper conditions were applied. The electrochemical performance of purified coke powder shows greatly improved electrochemical performance. The as-purified coke powder presented an initial reversible capacity of 257.4 mAh/g and a retention rate of 95% after 50 cycles. The proposed purification process paves a way to prepare a promising anode material with good performance with low cost of coke powder for Li-ion batteries.

关 键 词:锂离子电池  提纯工艺  焦粉  阳极  煤基  电化学性能  净化过程  氢氟酸

Purification process of coal-based coke powder as anode for Li-ion batteries
YANG Juan,MA Lu-lu,ZHOU Xiang-yang.Purification process of coal-based coke powder as anode for Li-ion batteries[J].Journal of Central South University of Technology,2014(3):857-861.
Authors:YANG Juan  MA Lu-lu  ZHOU Xiang-yang
Affiliation:[1]Powder Metallurgy Research Institute, Central South University, Changsha 410083, China [2]School of Metalllurgy and Environment, Central South University, Changsha 410083, China
Abstract:purification process coal-based coke powder anode material Li-ion batteries
Keywords:purification process  coal-based coke powder  anode material  Li-ion batteries
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