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糠醛的电化学聚合
引用本文:付艳辉,王立世.糠醛的电化学聚合[J].广东电力,2012(2):9-11,39.
作者姓名:付艳辉  王立世
作者单位:华南理工大学化学与化工学院
基金项目:国家自然科学基金资助项目(21175047)
摘    要:变压器油中糠醛的含量是预测变压器故障的重要参数。为了验证在乙腈溶剂中检测糠醛的可行性,以乙腈为溶剂,高氯酸钠和氢氧化钠为支持电解质,在0.5~2.3V电位范围内,采用循环电压一电流法,使糠醛在玻碳电极上形成致密的聚合物膜。聚合物膜在波长约460nm处有明显的可见光吸收,随着溶液中糠醛浓度的增大和扫描圈数的增加,聚合物膜在此处波长下的吸光度增大。实验结果表明,此法用于检测糠醛不太理想。

关 键 词:变压器油  糠醛  电化学聚合  有机相

Electrochemical Polymerization of Furfural
FU Yanhui,WANG Lishi.Electrochemical Polymerization of Furfural[J].Guangdong Electric Power,2012(2):9-11,39.
Authors:FU Yanhui  WANG Lishi
Affiliation:(School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou,Guangdong 510640,China)
Abstract:Furfural content in transformer oil is an important parameter for forecasting transformer failure.In order to prove the feasibility of detecting furfural in acetonitrile solvent,sodium perchlorate and sodiumhydroxide are taken as supporting electrolyte and dense polyfurfural membrane is formed on glass carbon electrode by adopting cyclic voltammetry in the potential range from 0.5 V to 2.3 V.The polyfurfural has a obvious visible absorption at the wavelength of 460 nm.With the increase of the concentration of furfural and the raising number of scanning,the absorption value of polyfurfural is strengthened.The result shows that this method is not good enough to detect furfural.
Keywords:transformer oil  furfural  electrochemical polymerization  organic phase
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