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废旧动力锂离子电池LiFePO4正极材料的再利用
引用本文:吕志,徐涛,王洋,赵煜娟.废旧动力锂离子电池LiFePO4正极材料的再利用[J].电池,2019,49(2):168-172.
作者姓名:吕志  徐涛  王洋  赵煜娟
作者单位:北京工业大学环境与能源工程学院,绿色催化与分离重点实验室,北京100124;北京工业大学环境与能源工程学院,绿色催化与分离重点实验室,北京100124;北京电动车辆协同创新中心,北京100124
基金项目:国家自然科学基金;北京市属高校高水平教师队伍建设支持计划
摘    要:通过热处理法和溶解法,对废旧动力锂离子电池电极活性物质磷酸铁锂(LiFePO4)进行处理.与700 t热处理再生的材料相比较,经350℃热处理的活性物质在结晶度、首次充放电和循环稳定性等方面表现较好。经350℃热处理的LiFePO4,以0.2 C在2.0~4.2 V循环,首次放电比容量达120 mAh/g,第40次循环的比容量为130 mAh/g,库仑效率保持在99%。

关 键 词:锂离子电池  废旧LiFePO4  正极材料  溶解法  热处理

Reuse of LiFePO4 cathode material from spent power Li-ion battery
LV Zhi,XU Tao,WANG Yang,ZHAO Yu-Juan.Reuse of LiFePO4 cathode material from spent power Li-ion battery[J].Battery Bimonthly,2019,49(2):168-172.
Authors:LV Zhi  XU Tao  WANG Yang  ZHAO Yu-Juan
Affiliation:(Beijing Key Laboratory for Green Catalysis and Separation,College of Environmental and Energy Engineering,Beijing University of Technology,Beijing 100124,China;Collaborative Innovation Center of Electric Vehicles in Beijing f Beijing 100124,China)
Abstract:The waste electrode materials were investigated by the heat treatment method and solvent method for recycling.Compared with the regenerated materials calcined at 700℃,the active materials treated at 350℃exhibited better electrochemical performance in crystallinity,initial charge-discharge and cycle stability.The initial specific discharge capacity of recycled LiFeP04 was 120 mAh/g calcined at 350℃and reached 130 mAh/g after 40 cycles at 0.2 C in 2.0-4.2 V and the Coulombic efficiency was still 99%.
Keywords:Li-ion battery  spent LiFeP04 cathode material  solvent method  heat treatment
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