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c-V2O5正极材料电化学性能的研究
引用本文:张勇,张翠芬,胡信国.c-V2O5正极材料电化学性能的研究[J].电池工业,2005,10(2):70-73.
作者姓名:张勇  张翠芬  胡信国
作者单位:哈尔滨工业大学应用化学系,黑龙江,哈尔滨,150001;江门三捷电池实业有限公司,广东,江门,529000;哈尔滨工业大学应用化学系,黑龙江,哈尔滨,150001
摘    要:介绍了用商品c—V2O5作正极材料组装成扣式试验电池并对电池进行了性能测试:从理论上分析了c-V2O5电极的电化学阻抗谱(EIS)、循环伏安特性(CV)、首次恒流放电(CD)和循环性能特性线(DC)。CD和DC测试结果显示,以60mA/g的电流密度充放电,其首次放电比容量高达220mAh/g,充放电效率可达97%,循环35次后,容量保持率仍可达47%。

关 键 词:可充锂电池  晶态V2O5  电化学性能  比容量
文章编号:1008-7923(2005)02-0070-04
修稿时间:2004年2月1日

Study of electrochemical characteristics of c- V2O5 as cathode materials for lithium rechargeable batteries
ZHANG Yong,ZHANG Cui- fen,HU Xin- guo.Study of electrochemical characteristics of c- V2O5 as cathode materials for lithium rechargeable batteries[J].Chinese Battery Industry,2005,10(2):70-73.
Authors:ZHANG Yong  ZHANG Cui- fen  HU Xin- guo
Abstract:Electrochemical characterization was carried out on commercial cryst al vanadium pentoxide (c-V2O5) to verify its application as cathode materials f or lithium rechargeable batteries by tests of EIS,CV,constant discharge (CD) a nd discharge/charge (DC). Analysis results of CD and DC indicated the sample ach ieved a high initial discharge specific capacity of approximate 220mAh/g and a c orresponding efficiency of 97%. Its preservation ratio of capacity still kept a s high as 47%even after 35 cycles at current density of 60mA/g.
Keywords:lithium rechargeable batteries  crystal vanadium pentoxide  electro  chemical characterization  specific capacity
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