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石墨烯的制备及其电化学性能
引用本文:杨常玲,刘云芸,孙彦平.石墨烯的制备及其电化学性能[J].电源技术,2010,34(2).
作者姓名:杨常玲  刘云芸  孙彦平
作者单位:1. 东华大学化学化工与生物工程学院,上海,201620;太原理工大学化工系,山西,太原,030024
2. 东华大学材料科学与工程学院,上海,201620
3. 太原理工大学化工系,山西,太原,030024
基金项目:国家自然科学基金资助项目(20776091)
摘    要:以石墨为原料,采用改进的Hummers方法制备氧化石墨,在水中经超声分散得到氧化石墨烯水溶胶,经硼氢化钠还原得到石墨烯聚集物。采用扫描电镜、原子力显微镜、激光粒度分析仪、BET氮气吸附仪对样品的形态、粒度分布和比表面积进行了表征。采用恒流充放电和循环伏安法研究了样品的充放电性能。结果表明,氧化石墨在水溶液中可以剥离成单片层结构,石墨烯聚集物比表面积为358m2/g,在10mA恒流下充放电,比电容为138.6F/g,充放电容量效率为98%。以5~50mV/s扫描速率进行循环伏安测试,石墨烯电极表现出良好的双电层电容器性能。

关 键 词:双电层电容器  石墨烯  充放电性能  

Preparation of graphene and its electrochemical performance
YANG Chang-ling,LIU Yun-yun,SUN Yan-ping.Preparation of graphene and its electrochemical performance[J].Chinese Journal of Power Sources,2010,34(2).
Authors:YANG Chang-ling  LIU Yun-yun  SUN Yan-ping
Affiliation:1. College of Chemistry;Chemical Engineering and Biotechnology;Donghua University;Shanghai 201620;China;2. Chemical Engineering Department;Taiyuan University of Technology;Taiyuan Shanxi 030024;3. College of Material Science and Technology;China
Abstract:Graphite was oxidized with modified Hummers's method and made into aqueous colloid with supersonic,in which the oxidized graphite were exfoliated into oxidized graphene layers. The graphene was gotten by reducing the graphene layers with sodium borohydride. The samples were characterized by scanning electron microscope, atomic force microscope, laser paricle analyzer and BET surface analyzer, while the charge-discharge performance was investigated by constant current and cyclic voltammetry methods. The results show that the oxidized graphene can be dispersed in aqueous solution in single sheets. The surface area of graphene is 358 m~2/g, and its charge capacitance at 10 mA is 138.6 Fig and the capacitance efficiency is 98%. The cyclic voltammetry test shows the graphene has good double layer electrical performance at scanning rates of 5-50 mV/s.
Keywords:double layer capacitor  graphene  charge-discharge performance  
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