| 多壁碳纳米管一离子液体修饰电极同位镀铋膜测定铅离子 |
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| 引用本文： | 张英,任旺,李敏娇.多壁碳纳米管一离子液体修饰电极同位镀铋膜测定铅离子[J].化学传感器,2011,31(3):62-65. |
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| 作者姓名： | 张英 任旺 李敏娇 |
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| 作者单位： | 四川理工学院化学与制药工程学院,四川自贡,643000 |
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| 基金项目： | 基金项目:四川省教育厅基金项目，四川理工学院科技项目 |
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| 摘 要： | 采用涂覆法制备多壁碳纳米管（MwCND-离子液体（BMIM]PF6）修饰电极，然后在其表面同位镀铋膜，研究Pb“在该修饰电极上的阳极溶出伏安行为。实验结果表明，pb^2＋在修饰电极上于一0．5V产生灵敏的溶出峰，Pb^2＋在3．0×10。～2．0x10^-5mol／L浓度范围内与其溶出峰电流呈良好的线性关系，检出限为...
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| 关 键 词： | 多壁碳纳米管 离子液体 修饰电极 同位镀铋膜 Pb(Ⅱ) |
Detection of lead ion using synchronous plating bismuth film on multi-walled carbon nanotube-ionic liquid modified electrode |
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| Zhang Ying,Ren Wang,Li Min-jiao.Detection of lead ion using synchronous plating bismuth film on multi-walled carbon nanotube-ionic liquid modified electrode[J].Chemical Sensors,2011,31(3):62-65. |
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| Authors: | Zhang Ying Ren Wang Li Min-jiao |
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| Affiliation: | Zhang Ying*,Ren Wang,Li Min-jiao(College of Chemical & Pharmaceutical Engineering,Sichuan University of Science & Engineering,Zigong 643000,China) |
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| Abstract: | The novel construction method for the detection of Pb（Ⅱ ） has been developed using synchronous plating bismuth film on the multi-walled carbon nanotube （MWCNT）-ionic liquid （BMIM]PFd modified electrode surface. The sensitive anodic stripping peak of Pb2＋ was obtained at the proposed sensor. Under the optimum conditions, stripping peak current of Pb2＋ has good linearity with concentration in the range of 3.0 × 10^-7 -2.0 × 10-5 tool/L, and the detection limit is 6.0 × 10^-8 mol/L. The resulting sensor is easy to prepare with good repeatability and can be used for determination of Pb（ Ⅱ ） ion in blood samples. |
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| Keywords: | multi-walled carbon nanotube ionic liquid modified electrode synchronous plating bismuth film rb（Ⅱ） |
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