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SrCO_3/TiO_2复合薄膜太阳能电池的性能研究
引用本文:吴小娟,蒋银花,吴敏,宋铂,孙岳明.SrCO_3/TiO_2复合薄膜太阳能电池的性能研究[J].化工新型材料,2010,38(4).
作者姓名:吴小娟  蒋银花  吴敏  宋铂  孙岳明
作者单位:东南大学化学化工学院,南京,211189
基金项目:国家重点基础研究发展规划(973计划) 
摘    要:采用丝网印刷法制备了SrCO3/TiO2复合薄膜电极;组装电池,研究了复合电极的光电性能。结果表明:敏化SrCO3/TiO2复合薄膜电极太阳能电池的短路电流密度、开路电压和填充因子比敏化TiO2电极电池均有增加,总的光电转换效率从3.01%提高到了3.53%,增加了17.3%。另外紫外光谱表明,SrCO3/TiO2复合薄膜电极吸附更多的染料。电化学阻抗谱研究表明,SrCO3/TiO2复合薄膜电极相对于空白TiO2电极有更小的阻抗,有利于电子在薄膜中的传输,提高了太阳能电池的性能。

关 键 词:SrCO_3/TiO_2复合薄膜电极  TiO_2电极  交流阻抗  太阳能电池

Study on performance of SrCO_3/TiO_2 composite film of solar cell
Wu Xiaojuan,Jiang Yinhua,Wu Min,Song Bo,Sun Yueming.Study on performance of SrCO_3/TiO_2 composite film of solar cell[J].New Chemical Materials,2010,38(4).
Authors:Wu Xiaojuan  Jiang Yinhua  Wu Min  Song Bo  Sun Yueming
Abstract:SrCO_3/TiO_2 composite film electrode was prepared by screen printing technique,and the photoelectric performances of solar cell based on SrCO_3/TiO_2 composite film electrode and TiO_2 film electrode were investigated.The results showed that addition of SrCO_3 could increase short-circuit current density(Jsc),open-circuit voltage (Voc) and fill factor (FF).And the energy conversion efficiency(η)of the solar cell was improved from 3.01%to 3.53%,an improvement of 17.3%.In addition,UV-Vis results showed dye adsorption of the SrCO_3/TiO_2 composite film electrode was larger than that of TiO_2 film electrode.Furthermore,electrochemical impedance spectrum (EIS) measurement confirmed that the SrCO_3/TiO_2 electrode had smaller resistance than TiO_2 electrode,which could improve the electron transport and the performance of solar cell.
Keywords:SrCO_3/TiO_2 composite film electrode  TiO_2 electrode  EIS  solar cell
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