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端羟基聚二甲基硅氧烷/蓖麻油改性聚氨酯嵌段共聚物的研究
引用本文:田军,薛群基.端羟基聚二甲基硅氧烷/蓖麻油改性聚氨酯嵌段共聚物的研究[J].高分子材料科学与工程,1998,14(6):38-40.
作者姓名:田军  薛群基
作者单位:中国科学院兰州化学物理研究所固体润滑开放实验室
摘    要:研究了端羟基的聚二甲基硅氧烷醇解蓖麻油改性聚氨酯预聚体共混改性。共聚物成膜后,分子结构中的有机硅链段更颂更倾向于表面聚集取向,而聚氨酯链段朝向内层。

关 键 词:聚氨酯  嵌段共聚物  改性  聚二甲基硅氧烷  蓖麻油

STUDY ON POLYDIMETHYLSILOXANE/POLYURETHANE BLOCK COPOLYMER
Tain Jun,Xue Qunji.STUDY ON POLYDIMETHYLSILOXANE/POLYURETHANE BLOCK COPOLYMER[J].Polymer Materials Science & Engineering,1998,14(6):38-40.
Authors:Tain Jun  Xue Qunji
Abstract:A series of poly(siloxane urethane) block copolymers were prepared by co condensation polymerization. The properties of these polymers were studied by DTA, TG, FT IR, TEM, contact angle and mechanical properties. These materials exhibit microphase separation of the hard and soft segments, however, the outside of siloxane group and the inside of polyurethane group in coating promot the adhesion, hardness, curing velocity and hydrophobicity of polymer coating.
Keywords:polydimethylsiloxane/polyurethane  block copolymer  coating  
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