| 高聚合度聚氯乙烯的溶度参数 |
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| 引用本文： | 张军,郑昌仁.高聚合度聚氯乙烯的溶度参数[J].高分子材料科学与工程,1994,10(5):50-54. |
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| 作者姓名： | 张军 郑昌仁 |
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| 作者单位： | 南京化工学院化工系 |
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| 基金项目： | 国家自然科学基金，江苏省科委自然科学基金 |
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| 摘 要： | 高聚合度聚氯乙烯的溶度参数与ＰＶＣ的溶度参数是否一致，尚无结论。本工作选择浓度滴定法，平衡溶胀法和粘度法等３种方法测定了聚合度为２５００的高聚合度聚氯乙烯树脂的溶度参数分别为２０．１３，２０．２５，２０．３０（Ｊ／ｃｍ＾３）１／２。实验结果表明，高聚合度聚氯乙烯树脂的聚合度虽然约为聚氯乙烯树脂的２－３倍，但对溶度参数值影响不大。上述３种测定方法中；浊度滴定法具有操作简单，重复性好等优点，是一种较好
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| 关 键 词： | 高聚合度 聚氯乙烯 溶度 参数 |
A DETERMINATION OF THE SOLUBILITY PARAMETER OF HIGH DEGREE OF POLYMERIZATION OF POLYVINYL CHLORIDE |
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| Zhang Jun,Zheng Changren and Yang Yufeng.A DETERMINATION OF THE SOLUBILITY PARAMETER OF HIGH DEGREE OF POLYMERIZATION OF POLYVINYL CHLORIDE[J].Polymer Materials Science & Engineering,1994,10(5):50-54. |
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| Authors: | Zhang Jun Zheng Changren and Yang Yufeng |
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| Affiliation: | Nanjing Institute of Chemical Technology |
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| Abstract: | By selected turbidity titration method,belanced swelling technique and intrinsic viscosity method,the determination results of solubility parameter of high degree of polymerization of polyvinyl chloride (HPVC)are 20.13(J/cm3)1/2,20.25(J/cm3)1/2 and 20.30(J/cm3)1/2.The experimental results showed that although the degree of polymerization of HPVC is 2or 3times than that of PVC,the solubility parameters of HPVC and PVC are very closed.Compared with balanced swelling technique and intrinsic viscosity method,turbidity titration method is uncomplicated,easy to operate and accurate.Turbidity titration method is a good method for the determination of the solubility parameter of polymers. |
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| Keywords: | s:high degree of polymerization of polyvinyl chloride solubility parameter turbidity titration method balanced swelling technique intrinsic viscosity method |
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