| 丙烯酰基苯并三氮唑的光引发聚合及产物光化学反应 |
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| 引用本文： | 李青山,叶大铿.丙烯酰基苯并三氮唑的光引发聚合及产物光化学反应[J].高分子材料科学与工程,1990,6(5):83-86. |
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| 作者姓名： | 李青山 叶大铿 |
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| 作者单位： | 齐齐哈尔轻工学院化工系
(李青山，李荫常)，武汉大学化学系(叶大铿) |
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| 摘 要： | 研究了丙烯酰基苯并三氮唑(ABT)、甲基丙烯酰基苯并三氮唑(MABT)的光自引发聚合行为及均聚物、共聚物的光化学反应。通过红外光谱、核磁共振谱和元素分析确定了单体、产物的结构,用紫外光谱和自由基捕捉剂探讨了光化学反应机理。
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| 关 键 词： | ABT 丙烯酰基 苯并三氮唑 聚合 |
SYNTHESIS AND PHOTOCHEMICALREACTION OF BENYOTRIAYOLE DERIVATIVES |
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| Li Qingshan,Li Yinchang Ye Dakeng.SYNTHESIS AND PHOTOCHEMICALREACTION OF BENYOTRIAYOLE DERIVATIVES[J].Polymer Materials Science & Engineering,1990,6(5):83-86. |
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| Authors: | Li Qingshan Li Yinchang Ye Dakeng |
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| Abstract: | In this paper, we report photopolymerization of acryloylleejotriajole (ABT) and Methy-lacryloylbenetriajole (MABT). It is found that these monomers can be polymerized by self initiation under the irradiation of UV, and formed a product with linear polymers and crosslinking polymers. The mechanism of this polymerzation process has been proved. The structure of monomers and polymers determined by IR, NMR, UV as well as elemental analysis. |
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| Keywords: | acryloylleejotriajole (ABT) photopolymerization photochemicalreactipn |
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