| 聚甲基丙烯酸烷基磺酸盐—聚双吡啶分子复合物研究 |
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| 引用本文： | 万国祥 王兵. 聚甲基丙烯酸烷基磺酸盐—聚双吡啶分子复合物研究[J]. 高分子材料科学与工程, 1990, 6(4): 83-87 |
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| 作者姓名： | 万国祥 王兵 |
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| 作者单位： | 中国科学院成都有机化学研究所，中国科学院成都有机化学研究所，成都科技大学，成都科技大学 83级毕业生，83级毕业生 |
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| 摘 要： | 高分子烷基磺酸盐与聚双吡啶在溶液中形成的大分子复合物具有很好的电化学稳定性。在三元溶剂中的最大溶解度为1.58g/ml;在—0.0v和—0.6v电压下分别显示无色和蓝紫色,响应时间为100ms。
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| 关 键 词： | 聚双吡啶 烷基磺酸盐 大分子复合物 |
STUDIES ON THE INTERMACROMOLECULE COMPLEX COMPOSED OF POLY (SULFOALKYL METHACRYLATE) AND POLYVIOLOGEN |
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| Wan Guoxian,Wang Bing,Liu Sanchao and Zhang Jing. STUDIES ON THE INTERMACROMOLECULE COMPLEX COMPOSED OF POLY (SULFOALKYL METHACRYLATE) AND POLYVIOLOGEN[J]. Polymer Materials Science & Engineering, 1990, 6(4): 83-87 |
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| Authors: | Wan Guoxian Wang Bing Liu Sanchao Zhang Jing |
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| Abstract: | In order to improve the electrostability, response speed, and solubility of polyviologen complexes, the intermacromolecule complex (PSHMA-m - PXV) based on poly (sulfoalkyl methacrylate) and polyviologen was synthesized. Cyclic Voltammogram shows that the complex film coated on a graphite electrode has a good electrochemical stability.Potential-step test gives a response speed of about 100ms. The phase diagrams of complex in the mixed solution composed of H2O, DMF, and salt (NaCl or NaBr) were also investigated. |
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| Keywords: | polyviologen poly ( sulfoakyl methacrylate ) intermacromolecule electrochr-omic display. |
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