| 电化学合成的含双键聚硅烷 |
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| 引用本文： | 吴市,陈来,张峰君,范雪骐,任慕苏,孙晋良.电化学合成的含双键聚硅烷[J].高分子材料科学与工程,2007,23(5):64-67. |
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| 作者姓名： | 吴市 陈来 张峰君 范雪骐 任慕苏 孙晋良 |
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| 作者单位： | 1. 上海大学材料科学与工程学院,上海,201800
2. 安徽建筑工业学院材料系,安徽,合肥,230022 |
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| 摘 要： | 采用电化学合成法,将甲基三氯硅烷与烯丙基氯进行聚合,合成出带有双键的聚硅烷,通过FT-IR,UV,1H-NM R,GPC表征了其结构,测定了产物的双键含量,并对产物进行了交联固化和高温裂解实验。结果表明,产物中双键保留率为8.2%,双键的引入使聚硅烷获得了很高的质量保留率及较高的陶瓷产率。
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| 关 键 词： | 聚硅烷 双键 电化学合成 |
| 文章编号： | 1000-7555（2007）05-0064-04 |
| 修稿时间： | 2006-07-10 |
Polysilane with Double Bonds by Eelctrochemical Synthesis |
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| WU Shi,CHEN Lai,ZHANG Feng-jun,FAN Xue-qi,REN Mu-su,SUN Jin-liang.Polysilane with Double Bonds by Eelctrochemical Synthesis[J].Polymer Materials Science & Engineering,2007,23(5):64-67. |
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| Authors: | WU Shi CHEN Lai ZHANG Feng-jun FAN Xue-qi REN Mu-su SUN Jin-liang |
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| Affiliation: | 1. School of Material Science and Engineering, Shanghai University, Shanghai 201800, China; 2. Department of Material Science and Engineering, Anhui Institute of Architecture and Industry, Hefei 230022, China |
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| Abstract: | A polysilane with double bonds was synthesized by electrochemical method,using methyltrichlorosilane and allyl chloride as monomers.The product was characterized by FT-IR,UV,1H-NMR,GPC.Its double-bond content was determined.The cross-linking and pyrolysis of it were studied.The results show that the retaining ratio of double bonds is 8.2%.The introduction of double bonds in polysilane brings forth much higher mass retaining ratio and better ceramic yield. |
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| Keywords: | polysilane double-bond electrochemical synthesis |
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