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线型缩聚中过量分数对聚合度的作用
引用本文:李万捷,赵彦生.线型缩聚中过量分数对聚合度的作用[J].高分子材料科学与工程,1994,10(4):135-137.
作者姓名:李万捷  赵彦生
作者单位:太原工业大学化工系高分子教研室
摘    要:本文根据过量分子分数的定义,推导出了聚合度关系式:Xn=1/(1-P+Pq),它能够用于计算缩聚反应体系的聚合度,控制聚合物的分子量,并以实例阐明了该公式的正确性。该式简便,易于记忆,在缩聚反应中具有普遍意义。

关 键 词:线型缩聚  聚合度  过量  高聚物

EXTRAMOLECULAR FRACTION EFFECT FOR DEGREE OF POLYMERIZATION
Li Wanjie and Zhao Yansheng.EXTRAMOLECULAR FRACTION EFFECT FOR DEGREE OF POLYMERIZATION[J].Polymer Materials Science & Engineering,1994,10(4):135-137.
Authors:Li Wanjie and Zhao Yansheng
Abstract:In this paper, the equation of was obtained in accordance with definition of extra molecular fraction. The equation can be used for calculating degree of polymerization and controlling molecular weight of polymers in polycondensation. The correctness of equation was elucidated by a few examples. It is more simple and easy memory. Therefore, the equation is possessed of the general significace in the polycondensation.
Keywords:s:linear polycondensation  degree of polymerization  extent of reaction  extra molecular fraction    
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