| 聚烯烃功能化的研究进展 |
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| 引用本文： | 洪浩群,何慧,贾德民,丁超,徐焕翔.聚烯烃功能化的研究进展[J].高分子材料科学与工程,2006,22(6):23-27. |
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| 作者姓名： | 洪浩群 何慧 贾德民 丁超 徐焕翔 |
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| 作者单位： | 华南理工大学材料科学与工程学院,广东,广州,510640 |
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| 基金项目： | 国家自然科学基金;广东省自然科学基金;华南理工大学校科研和教改项目 |
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| 摘 要： | 聚烯烃的功能化方法可分为:直接共聚法、反应性基团功能化和后功能化。与另外两种功能化方法相比,后功能化法的研究和应用较为广泛。本文重点介绍近年来后功能化的新技术如等离子体接枝、超临界二氧化碳接枝、固相力化学接枝和缩合聚合接枝以及传统方法比如溶液接枝法、辐射接枝法和固相接枝法的更新与改进。功能化聚烯烃对聚合物填充体系和共混体系有良好的增容作用。
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| 关 键 词： | 聚烯烃 功能化 后功能化 接枝 |
| 文章编号： | 1000-7555（2006）06-0023-05 |
| 收稿时间： | 2005-07-25 |
| 修稿时间： | 2005-11-04 |
Advances in Polyolefins Functionallization |
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| HONG Hao-qun,HE Hui,JIA De-min,DING Chao,XU Huan-xiang.Advances in Polyolefins Functionallization[J].Polymer Materials Science & Engineering,2006,22(6):23-27. |
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| Authors: | HONG Hao-qun HE Hui JIA De-min DING Chao XU Huan-xiang |
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| Affiliation: | College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China |
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| Abstract: | Polyolefins functionallization mainly consists of copolymerization,reactive functionallization and post-functionallization.Compared to the other functional methods,post-functionallization are more widely researched and applied.Emphasis is laid on the new methods of post-functionallization in terms of plasma graft copolymerization,supercritical carbon dioxide graft copolymerization and solid state mechanical chemical graft copolymerization,and some renovations to the traditional post-functionallization in terms of solvent graft copolymerization,radiation graft copolymerization and solid phase graft copolymerization.Functional polyolefins are excellent compatibilizers for polymer composites and blends. |
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| Keywords: | polyolefins functionallization post-functionallization graft |
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