| 多官能团环氧树脂体系的固化反应 |
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| 引用本文： | 周正伟,白瑞成,任慕苏,孙晋良,周泽,胡清平,汪传斌.多官能团环氧树脂体系的固化反应[J].高分子材料科学与工程,2011(8):61-64. |
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| 作者姓名： | 周正伟 白瑞成 任慕苏 孙晋良 周泽 胡清平 汪传斌 |
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| 作者单位： | 上海大学复合材料研究中心;远东控股集团有限公司 |
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| 基金项目： | 上海市重点学科建设项目(s30107);江苏省科技厅资助课题(BM2009514) |
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| 摘 要： | 采用非等温差示扫描量热（DSC）对多官能团环氧树脂体系固化反应进行了研究,确定了环氧树脂所用固化剂为甲基纳迪克酸酐（MNA）。对AG-70/MNA/2-乙基-4-甲基咪唑（EMI-2,4）环氧树脂体系在不同升温速率下的固化反应进行测试,根据DSC曲线,用温度-升温速率外推法,求出环氧树脂体系的三个特征温度,温度参数能为...
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| 关 键 词： | 环氧树脂 固化反应 差示扫描量热 动力学模型 |
Curing Reaction of Multifunctional Epoxy Resins |
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| Zhengwei Zhou,Ruicheng Bai,Musu Ren,Jinliang Sun,Ze Zhou,Qingping Hu,Chuanbin Wang.Curing Reaction of Multifunctional Epoxy Resins[J].Polymer Materials Science & Engineering,2011(8):61-64. |
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| Authors: | Zhengwei Zhou Ruicheng Bai Musu Ren Jinliang Sun Ze Zhou Qingping Hu Chuanbin Wang |
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| Affiliation: | 1.Composite Materials Research Center,Shanghai University,Shanghai 200072,China;2.Far East Holding Group Co.,Ltd.,Yixing 214257,China) |
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| Abstract: | The curing reaction of multifunctional epoxy resin system was studied by using non-isothermal DSC(differential scanning calorimetry),methyl nadic anhydride(MNA) as curing agent was determined.And then the curing reactivity for a system of AG-70/MNA/2-ethyl-4-methylimidazole(EMI-2,4) was measured at different heating rates.According to the DSC curves,the curing parameters were obtained by using T-β curve extrapolation,the temperature parameters could supply a guidance to the proper curing process.The kinetic parameters of the curing reaction of AG-70 epoxy resin system were calculated by using Kissinger and Crane equation,the kinetic model based on the nth order reaction equation was set up.Finally the curves of degree of cure a vs.temperature and time,rate of reaction dα/dt vs.temperature and time were analyzed respectively,it shows that the calculated data is in good agreement with that theoretically. |
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| Keywords: | epoxy resin cure reaction DSC kinetic model |
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