| 反向微乳液法合成导电聚苯胺纳米粒子 |
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| 引用本文： | 井新利,郑茂盛,蓝立文. 反向微乳液法合成导电聚苯胺纳米粒子[J]. 高分子材料科学与工程, 2000, 16(2): 23-25 |
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| 作者姓名： | 井新利 郑茂盛 蓝立文 |
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| 作者单位： | 1. 西安交通大学高分子材料系,陕西西安,710049
2. 西北工业大学化工系,陕西西安,710072 |
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| 基金项目： | 航空科学基金!资助课题 (97G5 3 0 76) |
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| 摘 要： | 以ＴｒｉｔｏｎＸ－１００为乳化剂、正己醇为助乳化剂,得到以苯胺盐酸盐为水相、正己烷为分散介质的反向（Ｗ／Ｏ）微乳液。进一步以过硫酸铵为氧化剂,合成了导电离子分材料聚苯胺的钠米粒子,对合成反应条件和产物的性能进行了初步的研究。
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| 关 键 词： | 微乳液 聚苯胺 导电聚合物 纳米粒子 乳液聚合 |
| 文章编号： | 1000-7555(2000)02-0023-03 |
| 修稿时间： | 1998-11-30 |
THE SYNTHESES OF CONDUCTING POLYANILINE NANO-PARTICLES THROUGH REVERSE MICROEMULSIONS |
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| JING Xin-li,ZHENG Mao-sheng,LAN Li-wen. THE SYNTHESES OF CONDUCTING POLYANILINE NANO-PARTICLES THROUGH REVERSE MICROEMULSIONS[J]. Polymer Materials Science & Engineering, 2000, 16(2): 23-25 |
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| Authors: | JING Xin-li ZHENG Mao-sheng LAN Li-wen |
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| Abstract: | The reverse(W/O) microemulsions in which aniline chloride is water phase and hexane is oil phase are prepared by use of Triton X 100 as emulsifier and hexanol as assistant emulsifier. In the microemulisions, conducting polyaniline nano particles are prepared by using ammonium persulfate as oxidant. The conditions of reaction and the products are investigated, too. The results show that the particle size increases with the raising of R (water mass/emulsifier mass), and the conductivity of polyaniline doped hydrochloride decrease with the raising of R and [ammonium persulfate]/[aniline]. |
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| Keywords: | microemulsions polyaniline conducting polymer nano particles |
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