| HPB－b－PMMA增容PVC／PE共混物球晶和结晶行为研究 |
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| 引用本文： | 左榘,王志刚,张邦华,周庆业,宋谋道.HPB－b－PMMA增容PVC／PE共混物球晶和结晶行为研究[J].高分子材料科学与工程,1996(2). |
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| 作者姓名： | 左榘 王志刚 张邦华 周庆业 宋谋道 |
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| 作者单位： | 南开大学化学系，南开大学高分子化学研究所 |
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| 摘 要： | 以小角激光散射（ＳＡＬＳ）和广角Ｘ光衍射（ＷＡＸＤ）技术，测定了氢化聚丁二烯－聚甲基丙烯酸甲基嵌段共聚物（ＨＰＢ－ｂ－ＰＭＭＡ）增容的聚氯乙烯（ＰＶＣ）和聚乙烯（ＰＥ）共混物的球晶形态和结晶度。从该共混物中ＰＥ的结晶状况得出，增容剂ＨＰＢ－ｂ－ＰＭＭＡｄ在降低ＰＥ结晶能力、增加ＰＥ／ＰＶＣ界面粘合并形成ＰＶＣ和ＰＥ相间的部分相容性有着重要的作用。
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| 关 键 词： | 氢化聚丁二烯－聚甲基内烯酸甲酯，聚乙烯／聚氯乙烯共混物，相容性 |
A STUDY OF SPHERULITE AND CRYSTALLIZATION OF BLEND PE/PVC WITH COMPATIBILIZER HPB-b-PMMA |
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| Zhuo Ju,Wang Zhigang.A STUDY OF SPHERULITE AND CRYSTALLIZATION OF BLEND PE/PVC WITH COMPATIBILIZER HPB-b-PMMA[J].Polymer Materials Science & Engineering,1996(2). |
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| Authors: | Zhuo Ju Wang Zhigang |
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| Abstract: | In this paper,the spherulitic morphology and crystailinity of blends PE/PVC with and without compatibilizer poly (hydrogenated butadiene-b-methylmethacrylate) copolymer (HPB-b PMMA)were determined by Small Angle Laser Scattering (SALS) and Wide Angle X-ray Diffraction (WAXD). From crystallization of PE,a conclusion that HPB b-PMMA glayed a very important role in decreasing the ability uf crystallization of PE, increasing adhesing of interface between phases of PE and PVC and forming partially compatibility of PE/PVC was withdrawn. |
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| Keywords: | s:poly (hydrogenated butadiene-b-methylmethacrylate) PE/PVC blend compatibility |
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