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气体辅助注射成型聚丙烯的多层次结构
引用本文:郑国强,杨伟,杨鸣波,陈静波,李倩,申长雨.气体辅助注射成型聚丙烯的多层次结构[J].高分子材料科学与工程,2009(3):92-95.
作者姓名:郑国强  杨伟  杨鸣波  陈静波  李倩  申长雨
作者单位:郑州大学材料科学与工程学院橡塑模具国家工程研究中心;四川大学高分子科学与工程学院高分子材料工程国家重点实验室;
基金项目:国家自然科学基金资助项目(50673067,10590351);;国家重点基础研究项目(2005CB623808)
摘    要:用扫描电镜(SEM)观察了气体辅助注射成型(GAIM)和常规注射成型(CIM)等规聚丙烯(iPP)在不同部位的结晶形态。发现CIM试样的"皮-芯"结构不明显,而GAIM试样在不同部位则形成了包括球晶、串晶和取向片晶,进而表现出明显的多层次结构。在结晶形态分析的基础上,初步探讨了GAIM制品多层次结构的形成机理。

关 键 词:气体辅助注射成型  串晶  气体穿透  皮-芯结构

Multi-Layered Structure of iPP Molded by Gas-Assisted Injection Molding
ZHENG Guo-qiang,YANG Wei,YANG Ming-bo,CHEN Jing-bo,LI Qian,SHEN Chang-yu.Multi-Layered Structure of iPP Molded by Gas-Assisted Injection Molding[J].Polymer Materials Science & Engineering,2009(3):92-95.
Authors:ZHENG Guo-qiang    YANG Wei  YANG Ming-bo  CHEN Jing-bo  LI Qian  SHEN Chang-yu
Affiliation:1.College of Material Science and Engineering;National Engineer Research Center for Advanced Polymer Processing Technology;Zhengzhou University;Zhengzhou 450002;China;2.College of Polymer Science and Engineering;State Key Laboratory of Polymer Materials Engineering;Sichuan University;Chengdu 610065;China
Abstract:In this study,iPP was molded by gas-assisted injection molding(GAIM) and conventional injection molding(CIM).After being etched chemically,multi-layer structure of these parts were investigated by scanning electronic microscopy.Owing to the larger size of the mold cavity,the multi-layered structure can not be observed in the CIM parts.However,for the GAIM parts molded under low and higher pressure respectively,a multi-layered structure,including shish-kebab(or naked shish),spherulite,is founded in different...
Keywords:gas-assisted injection molding  shish kebab  gas penetration  skin-core structure  
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