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共聚酯固相聚合动力学研究
引用本文:邓建元,武荣瑞.共聚酯固相聚合动力学研究[J].高分子材料科学与工程,1995,11(3):29-31.
作者姓名:邓建元  武荣瑞
作者单位:中国化工信息中心,北京服装学院
摘    要:对两种共聚酯作了固相聚合动力学研究,其动力学符合二级反应方程。求出了反应速度常数k和活化能Ea。结果表明,共聚酯固相聚合反应速度明显快于纯聚酯。

关 键 词:固相聚合  动力学  共聚酯  聚酯

STUDY ON KINETICS OF SOLID STATE POLYCONDENSATION OF COPOLYESTERS
Deng Jianyuan.STUDY ON KINETICS OF SOLID STATE POLYCONDENSATION OF COPOLYESTERS[J].Polymer Materials Science & Engineering,1995,11(3):29-31.
Authors:Deng Jianyuan
Abstract:A study on kinetics of solid state ploycondensation of two kinds of copolyesters copolymers of polyethylene terephthalate is carried out.One copolycondensation monomer is isophthalic acid and the other adipic acid.The kinetics are conformarity with second-order reaction equation,the reaction rate constant value(k) and reaction energy(Ea) are obtained.It is shown,that the reaction rate on solid state polycondensation of copolyesters is obviously faster than pure polyester(PET).
Keywords:s:solid polycondensation  kinetics  copolyester  
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