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改性金刚烷共聚物的制备与性能
引用本文:梁成锋,郭建维,刘卅,邓志城,彭进平,崔亦华. 改性金刚烷共聚物的制备与性能[J]. 高分子材料科学与工程, 2010, 0(4): 135-138
作者姓名:梁成锋  郭建维  刘卅  邓志城  彭进平  崔亦华
作者单位:广东工业大学轻工化工学院;华南理工大学材料科学与工程学院;
基金项目:广州市科技计划项目(2007Z3-D0051)
摘    要:采用不同方法制备了金刚烷胺(AMA)改性的丙烯酸(AA)-N-乙烯基吡咯烷酮(NVP)共聚物(AMA-m-P(AA-co-NVP))。研究了原料配比、合成方法对改性共聚物中AMA的含量及溶解性的影响,采用红外光谱、热分析、凯氏定氮等分析测试方法对改性共聚物进行了结构表征。结果表明,AMA与AA通过-COOH.NH2-键连接,加热到120℃以上会导致-COOH.NH2-键脱水,转变为酰胺键;反应时间影响AMA含量;合成方法影响其溶解性。

关 键 词:金刚烷胺  N-乙烯基吡咯烷酮  改性  溶解性

Preparation and Properties of Modified Adamantane Copolymer
LIANG Cheng-feng,GOU Jian-wei,LIU Sa,DENG Zhi-cheng,PENG Jin-ping,CUI Yi-hua. Preparation and Properties of Modified Adamantane Copolymer[J]. Polymer Materials Science & Engineering, 2010, 0(4): 135-138
Authors:LIANG Cheng-feng  GOU Jian-wei  LIU Sa  DENG Zhi-cheng  PENG Jin-ping  CUI Yi-hua
Affiliation:1. Faculty of Chemical Engineering & Light Industry;Guangdong University of Technology;Guangzhou 510006;China;2. Department of Materials Science and Engineering;South China University of Technology;Guangzhou 510640;China
Abstract:N-vinylpyrrolidone-acrylic acid copolymers modified by amantadine(AMA-m-P(AA-co-NVP)) were prepared by different methods. Influences of reactants ratio and preparing technology on AMA content and solubility of the modified adamantane copolymer were investigated. The structures and properties of AMA-m-P(AA-co-NVP) were characterized by Fourier transform infrared spectrum(FT-IR),thermal analysis and Kjeldahl method. The results show that AMA is linked with the pendant group COOH of the AA-NVP copolymer in the...
Keywords:amantadine  vinyl pyrrolidone  modification  solubility  
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