| 改性金刚烷共聚物的制备与性能 |
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| 引用本文： | 梁成锋,郭建维,刘卅,邓志城,彭进平,崔亦华. 改性金刚烷共聚物的制备与性能[J]. 高分子材料科学与工程, 2010, 0(4): 135-138 |
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| 作者姓名： | 梁成锋 郭建维 刘卅 邓志城 彭进平 崔亦华 |
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| 作者单位： | 广东工业大学轻工化工学院;华南理工大学材料科学与工程学院; |
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| 基金项目： | 广州市科技计划项目(2007Z3-D0051) |
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| 摘 要： | 采用不同方法制备了金刚烷胺(AMA)改性的丙烯酸(AA)-N-乙烯基吡咯烷酮(NVP)共聚物(AMA-m-P(AA-co-NVP))。研究了原料配比、合成方法对改性共聚物中AMA的含量及溶解性的影响,采用红外光谱、热分析、凯氏定氮等分析测试方法对改性共聚物进行了结构表征。结果表明,AMA与AA通过-COOH.NH2-键连接,加热到120℃以上会导致-COOH.NH2-键脱水,转变为酰胺键;反应时间影响AMA含量;合成方法影响其溶解性。
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| 关 键 词： | 金刚烷胺 N-乙烯基吡咯烷酮 改性 溶解性 |
Preparation and Properties of Modified Adamantane Copolymer |
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| LIANG Cheng-feng,GOU Jian-wei,LIU Sa,DENG Zhi-cheng,PENG Jin-ping,CUI Yi-hua. Preparation and Properties of Modified Adamantane Copolymer[J]. Polymer Materials Science & Engineering, 2010, 0(4): 135-138 |
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| Authors: | LIANG Cheng-feng GOU Jian-wei LIU Sa DENG Zhi-cheng PENG Jin-ping CUI Yi-hua |
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| Affiliation: | 1. Faculty of Chemical Engineering & Light Industry;Guangdong University of Technology;Guangzhou 510006;China;2. Department of Materials Science and Engineering;South China University of Technology;Guangzhou 510640;China |
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| Abstract: | N-vinylpyrrolidone-acrylic acid copolymers modified by amantadine(AMA-m-P(AA-co-NVP)) were prepared by different methods. Influences of reactants ratio and preparing technology on AMA content and solubility of the modified adamantane copolymer were investigated. The structures and properties of AMA-m-P(AA-co-NVP) were characterized by Fourier transform infrared spectrum(FT-IR),thermal analysis and Kjeldahl method. The results show that AMA is linked with the pendant group COOH of the AA-NVP copolymer in the... |
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| Keywords: | amantadine vinyl pyrrolidone modification solubility |
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