Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate |
| |
| Affiliation: | 1. College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, PR China;2. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, PR China;3. Laboratory of New Energy&New Function Materials, College of Chemistry and Chemical Engineering, Yan''an University, Yan''an, Shaanxi 716000, PR China;1. Pharmacy College, Henan University of Traditional Chinese Medicine, Zhengzhou, China;2. The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China |
| |
| Abstract: | Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase 1 of composition Cu(Py2C6H12)3(NO3)2]·2Cu(Py2C6H12)2(H2O)(NO3)]·2(NO3)·EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition Cu2(Py2C6H12)4(H2O)2]·(NO3)4·(Py2C6H12)·(EtOH)·2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
