| 超细镍粉的溶液还原法制备研究 |
| |
| 引用本文： | 张楠,翟秀静.超细镍粉的溶液还原法制备研究[J].功能材料,1999,30(3):263-264,267. |
| |
| 作者姓名： | 张楠 翟秀静 |
| |
| 作者单位： | 东北大学材料与冶金学院 |
| |
| 摘 要： | 以ＮｉＳＯ４．６Ｈ２Ｏ为原料，Ｎ２Ｈ４．Ｈ２Ｏ为还原剂，ＮａＯＨ调节溶液的ＰＨ值，控制反应条件为：Ｎｉ＾ｗ２＋的浓度１．０ｍｏｌ．Ｌ＾－１；Ｎ２Ｈ４．Ｈ２Ｏ／Ｎｉ＾２＋为２．０；ＮａＯＨ／Ｎｉ＾２＋的１．０，反应温度为９０℃，将得到的沉淀物洗涤，干燥，得到了平均粒度为６２ｎｍ的超细镍粉，考察了反应条件对还原反应的影响，并对制备的粉末采用ＴＥＭ，ＸＲＤ，ＩＡＳ及ＢＥＴ法进行了表征，结果表明，本法制力
|
| 关 键 词： | 镍粉 溶液还原 制备 超细粉末 |
Research of Preparation of Ultrafine Nickel Powders bySolution Reduction Method |
| |
| ZHANG Nan,ZHAI Xiujing,ZHAI Yuchun Material and Metallurgy College,Northeastern University,Shenyang,China.Research of Preparation of Ultrafine Nickel Powders bySolution Reduction Method[J].Journal of Functional Materials,1999,30(3):263-264,267. |
| |
| Authors: | ZHANG Nan ZHAI Xiujing ZHAI Yuchun Material and Metallurgy College Northeastern University Shenyang China |
| |
| Affiliation: | ZHANG Nan,ZHAI Xiujing,ZHAI Yuchun Material and Metallurgy College,Northeastern University,Shenyang,110006,China |
| |
| Abstract: | By using NiSO46H2O as material,N2H4H2O as reductant,NaOH adjusting pH value of the solution,ultrafine nickel powders can be prepared.The condition of reaction is as follows:concentration of Ni2+ is 1.0molL-1,N2H4H2O/Ni2+ is 2.0,NaOH/Ni2+ is 1.0 and reaction temperature is 90.The powders prepared were characterized by TEM,XRD,IAS,and BET method.The results show that the nickel powders prepared are spherical and average size is 62nm with narrow size distribution.The amount of NaOH affects the purity of nickel powders. |
| |
| Keywords: | ultrafine powders nickel powders solution reduction |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
