| 双连续相微乳液聚合制备多孔材料 |
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| 引用本文： | 杨杰,舒武炳,秦卫.双连续相微乳液聚合制备多孔材料[J].功能材料,2010,41(1). |
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| 作者姓名： | 杨杰 舒武炳 秦卫 |
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| 作者单位： | 西北工业大学,理学院,陕西,西安,710072 |
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| 基金项目： | 西北工业大学研究生创新实验中心资助项目(09009) |
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| 摘 要： | 反相(W/O)或双连续相微乳液聚合制备多孔材料是近年研究的热点。研究了双连续相微乳液聚合制备多孔吸油材料:以甲基丙烯酸甲酯、甲基丙烯酸丁酯为共聚单体(油相),水/乙醇为混合水相,偶氮二异丁腈为引发剂,十二烷基硫酸钠为乳化剂,调节油相和水相比例,配制出双连续相微乳液。聚合在无搅拌下进行。对聚合物进行SEM观测表明,当混合水相含量在30%～43%(质量分数,下同)区域内,得到连续开孔材料。仅对多孔材料制备工艺进行研究分析及孔特性进行了表征,吸油材料的研究将在后续文章中报道。
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| 关 键 词： | 微乳液聚合 双连续相 多孔材料 |
Research on porous materials from bicontinuous microemulsion polymerization |
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| YANG Jie,SHU Wu-bing,QIN Wei.Research on porous materials from bicontinuous microemulsion polymerization[J].Journal of Functional Materials,2010,41(1). |
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| Authors: | YANG Jie SHU Wu-bing QIN Wei |
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| Abstract: | The preparation of porous materials by Inverse microemulsion (W/O) or bicontinuous microemulsion has been an attractive research.This task makes an study on porous oil absorption material from microemulsion polymerization:methyl methacrylate and butyl methacrylate were in the presence of comonomer (oil phrase) while sodium dodecyl sulfate and n-butanol formed a emulsification system,ethanol was dispersed in the water to form a mixture aqueous with azobisisobutyronitrile as an initiator and adjust the propor... |
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| Keywords: | microemulsion bicontinuous microemulsion porous materials |
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