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苯乙烯-二乙烯苯树脂负载双核钴酞菁对巯基乙醇的催化性能
引用本文:姚玉元,吕汪洋,王秀华,陈文兴,黄显雯.苯乙烯-二乙烯苯树脂负载双核钴酞菁对巯基乙醇的催化性能[J].功能材料,2009,40(2).
作者姓名:姚玉元  吕汪洋  王秀华  陈文兴  黄显雯
作者单位:浙江理工大学"先进纺织材料与制备技术"教育部重点实验室,浙江,杭州,310018  
基金项目:教育部长江学者和创新团队发展计划创新团队资助项目,国家自然科学基金,高等学校博士学科点专项科研基金,浙江省自然科学基金 
摘    要:双棱钴酞菁(Co2Pc2)以共价键负载到苯乙烯-二乙烯苯树脂(resin)上得到一种新型的催化功能性材料(resin-Co2Pc2).考察了pH、催化剂量和温度对resin-Co2Pc2催化巯基乙醇的影响.实验结果表明,resin-Co2Pc2在pH=11儿时催化活性达到最大;催化活性随反应温度升高而提高,此催化反应为吸热反应,而且resin-Co2Pc2经多次重复使用后其催化活性基本保持不变,具有很好的重复使用性能.

关 键 词:钴酞菁  催化氧化  功能材料  巯基乙醇

The catalytic activity of styrene-divinyl benzene resin supported binuclear cobalt phthalocyanine on 2-mercaptoethanol
YAO Yu-yuan,LV Wang-yang,WANG Xiu-hua,CHEN Wen-xing,HUANG Xian-wen.The catalytic activity of styrene-divinyl benzene resin supported binuclear cobalt phthalocyanine on 2-mercaptoethanol[J].Journal of Functional Materials,2009,40(2).
Authors:YAO Yu-yuan  LV Wang-yang  WANG Xiu-hua  CHEN Wen-xing  HUANG Xian-wen
Affiliation:Key Laboratory of Advanced Textile Materials and Manufacturing Technology;Ministry of Education;Zhejiang Sci-Tech University;Hangzhou 310018;China
Abstract:Binuclear cobalt phthalocyanine(Co2Pc2) was supported on styrene-divinyl benzene resin by covalent bond to obtain a novel catalytic functional material,resin-Co2Pc2.The effects of pH,the quantity of resin-Co2Pc2 and temperature on the catalytic activity of resin-Co2Pc2 on 2-mercaptoethanol were investigated.The results showed that resin-Co2Pc2 had high catalytic activity on 2-mercaptoethanol,and even the catalytic activity was the best at pH 11.The reaction can further be enhanced with the quantity of resin...
Keywords:binuclear cobalt phthalocyanine  catalytic oxidation  functional materials  2-mercaptoethanol  
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