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模板法制备聚苯胺空心微球材料及其电化学性能
引用本文:黄彬,江奇,谢德钰,陈海明,和腊梅,赵勇.模板法制备聚苯胺空心微球材料及其电化学性能[J].功能材料,2011,42(1):144-147.
作者姓名:黄彬  江奇  谢德钰  陈海明  和腊梅  赵勇
作者单位:西南交通大学超导研究开发中心材料先进技术教育部重点实验室;School of Materials Science and Engineering;University of New South Wales;
基金项目:国家自然科学基金资助项目(50907056,50872116); 长江学者与创新团队计划资助项目(IRT0751); 中央高校基本科研业务费专项资金资助项目(SWJTU09CX053); 四川省科技攻关计划资助项目(2006Z02K-006-1); 四川省应用基础研究基金资助项目(2008JY0061); 西南交通大学基础科学研究基金资助项目(2007B20);西南交通大学工程实践资助项目(11-1)
摘    要:运用模板法,以聚苯乙烯(PS)胶体粒子为微球核,使苯胺单体吸附于PS胶体粒子表面,然后利用原位的化学氧化聚合,制备出聚苯乙烯/聚苯胺(PS/PANI)核壳材料.然后再将PS微球核溶解,最终得到PANl空心微球材料.采用傅立叶变换红外光谱、扫描电子显微镜对所得材料进行成分和形貌的分析.利用循环伏安法、恒流充放电测试法和循...

关 键 词:模板法  聚苯胺空心微球  电化学性能

Preparation of polyaniline hollow micro-sphere materials with template method and its electrochemical properties
HUANG Bin,JIANG Qi,XIE De-yu,CHEN Hai-ming,HE La-mei,ZHAO Yong.Preparation of polyaniline hollow micro-sphere materials with template method and its electrochemical properties[J].Journal of Functional Materials,2011,42(1):144-147.
Authors:HUANG Bin  JIANG Qi  XIE De-yu  CHEN Hai-ming  HE La-mei  ZHAO Yong
Affiliation:HUANG Bin1,JIANG Qi1,XIE De-yu1,CHEN Hai-ming1,HE La-mei1,ZHAO Yong 1,2 (1.Key Laboratory of Advanced Technologies of Materials,Ministry of Education of China,and Superconductivity Research and Development Centre,Southwest Jiaotong University,Chengdu 610031,China,2.School of Materials Science and Engineering,University of New South Wales,Sydney 2052 NSW,Australia)
Abstract:The polystyrene(PS) micro-sphere was used as the template to prepare PS/polyaniline(PANI) core-shell materials.The aniline monomers were first absorbed on the surface of the PS micro-sphere,and then were polymerized to PANI by the chemical oxygenation method.As this,the PS/PANI materials were obtained.After that,the PS micro-spheres were removed by dissolution and the PANI hollow micro-spheres were obtained.The obtained materials were characterized by the Fourier transform infrared spectroscope,scanning ele...
Keywords:template method  PANI hollow micro-sphere  electrochemical performances  
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