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VO2/TiN Plasmonic Thermochromic Smart Coatings for Room‐Temperature Applications
Authors:Qi Hao  Wan Li  Huiyan Xu  Jiawei Wang  Yin Yin  Huaiyu Wang  Libo Ma  Fei Ma  Xuchuan Jiang  Oliver G Schmidt  Paul K Chu
Affiliation:1. Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong, China;2. Institute for Integrative Nanosciences, Leibniz IFW Dresden, Dresden, Germany;3. State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, Shaanxi, China;4. Center for Biomedical Materials and Interfaces, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, P.R. China;5. Department of Chemical Engineering, Monash University, Clayton, VIC, Australia;6. Material Systems for Nanoelectronics, Chemnitz University of Technology, Chemnitz, Germany
Abstract:Vanadium dioxide/titanium nitride (VO2/TiN) smart coatings are prepared by hybridizing thermochromic VO2 with plasmonic TiN nanoparticles. The VO2/TiN coatings can control infrared (IR) radiation dynamically in accordance with the ambient temperature and illumination intensity. It blocks IR light under strong illumination at 28 °C but is IR transparent under weak irradiation conditions or at a low temperature of 20 °C. The VO2/TiN coatings exhibit a good integral visible transmittance of up to 51% and excellent IR switching efficiency of 48% at 2000 nm. These unique advantages make VO2/TiN promising as smart energy‐saving windows.
Keywords:plasmonics  smart coatings  thermochromic  titanium nitride  vanadium dioxide
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