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以改性丙烯酸酯乳液为连结料的水性油墨制备
引用本文:钟泽辉,卞喻,徐军,孔繁辉.以改性丙烯酸酯乳液为连结料的水性油墨制备[J].包装工程,2013,34(21):95-99.
作者姓名:钟泽辉  卞喻  徐军  孔繁辉
作者单位:1. 湖南工业大学, 株洲412007; 2. 常德金鹏印务有限公司, 常德415000,湖南工业大学, 株洲412007,常德金鹏印务有限公司, 常德415000,常德金鹏印务有限公司, 常德415000
基金项目:湖南省自然科学基金资助项目(12JJ9012)
摘    要:采用半连续乳化法制备了双丙酮丙烯酰胺-己二酸二酰肼改性的丙烯酸酯乳液,配以蓝色碱性颜料配制成水性油墨,讨论了交联体系改性对水性油墨各性能的影响。结果表明,随着DAAM-ADH 的质量分数由0 增加到3%,丙烯酸酯乳液固含量增加,粒径变小,水性油墨的黏度增大,稳定性得到了改善,附着牢度增大,耐水性耐酸碱性增强;当DAAM-ADH 的质量分数继续增加至5%时,水性油墨的黏度显著增大,导致物理凝胶。

关 键 词:水性丙烯酸酯乳液    水性油墨    交联改性    双丙酮丙烯酰胺
收稿时间:2012/11/25 0:00:00
修稿时间:2013/11/10 0:00:00

Preparation of Water-based Ink Based on Modified Acrylate Emulsion
ZHONG Ze-hui,BIAN Yu,XU Jun and KONG Fan-hui.Preparation of Water-based Ink Based on Modified Acrylate Emulsion[J].Packaging Engineering,2013,34(21):95-99.
Authors:ZHONG Ze-hui  BIAN Yu  XU Jun and KONG Fan-hui
Affiliation:1. Hunan University of Technology, Zhuzhou 412007, China; 2. Hunan Changde Goldroc Printing Co. , Ltd. , Changde 415000, China,Hunan University of Technology, Zhuzhou 412007, China,Hunan Changde Goldroc Printing Co. , Ltd. ,Changde 415000, China and Hunan Changde Goldroc Printing Co. , Ltd. ,Changde 415000, China
Abstract:Water-based ink was prepared by mixing diacetone acrylamide-adipate hydrazide modified acrylate emulsion, which was synthesized by semi-continuous emulsion polymerization with blue alkaline pigment. The effect of crosslinking system modification on performances of the water-based ink was studied. The results showed that when the content of DAAM-ADH increase to 3% from 0%, the solid content of acrylate emulsion increases, the particle size decreases, the viscosity of water-based ink increases, the stability improved, the adhesion increases, the water resistance and acid-alkali resistance became stronger. When the content of DAAM-ADH is up to 5%, the viscosity of water-based ink increase significantly, this results in physical gel.
Keywords:waterborne acrylic emulsion  water-based ink  crosslinking modification  diacetone acrylamide
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