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Protective Effect of the Sputtered TiAlCrAg Coating on the High-Temperature Oxidation and Hot Corrosion Resistance of Ti-Al-Nb Alloy
作者姓名:Yanjun XI  Fuhui WANG and Lianlong HEState Key Laboratory for Corrosion & Protection  Institute of Metai Research  Chinese Academy of Sciences  Shenyang  ChinaShenyang National Laboratory for Materials Science  Institute of Metai Research  Chinese Academy of Sciences  Shenyang  China
作者单位:Yanjun XI,Fuhui WANG and Lianlong HEState Key Laboratory for Corrosion & Protection,Institute of Metai Research,Chinese Academy of Sciences,Shenyang 110016,ChinaShenyang National Laboratory for Materials Science,Institute of Metai Research,Chinese Academy of Sciences,Shenyang 110016,China
摘    要:The effect of a sputtered Ti-48AI-8Cr-2Ag (at. pct) coating on the oxidation resistance of the cast Ti-46.5AI-5Nb (at. pct) alloy was investigated in air at 1000-1100℃. Hot corrosion in molten 75 wt pct Na2SO4+25 wt pct K2SO4 was investigated at 900℃. The scale on the cast TiAINb tends to spall in air, while the scale on coating is very adherent. The sputtered Ti-48AI-8Cr-2Ag coating remarkably improved high temperature oxidation resistance of the cast Ti-46.5AI-5Nb alloy because of the formation of an adherent Al2O3 scale. Due to the inward diffusion of Cr, Kirkendall voids were found at the coating/substrate interface. TiAICrAg coating provided excellent hot corrosion resistance for TiAINb alloy in molten 75 wt pct Na2SO4+25 wt pct K2S04 at 900℃ due to the formation of a continuous Al2O3 scale.


Protective Effect of the Sputtered TiAlCrAg Coating on the High-Temperature Oxidation and Hot Corrosion Resistance of Ti-Al-Nb Alloy
Yanjun XI,Fuhui WANG and Lianlong HEState Key Laboratory for Corrosion & Protection,Institute of Metai Research,Chinese Academy of Sciences,Shenyang ,ChinaShenyang National Laboratory for Materials Science,Institute of Metai Research,Chinese Academy of Sciences,Shenyang ,China.Protective Effect of the Sputtered TiAlCrAg Coating on the High-Temperature Oxidation and Hot Corrosion Resistance of Ti-Al-Nb Alloy[J].Journal of Materials Science & Technology,2004,20(6):724-727.
Authors:Yanjun XI  Fuhui WANG  Lianlong HE
Affiliation:State Key Laboratory for Corrosion & Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
Abstract:The effect of a sputtered Ti-48Al-8Cr-2Ag (at. pct) coating on the oxidation resistance of the cast Ti-46.5Al-5Nb (at. pct) alloy was investigated in air at 1000~1100℃. Hot corrosion in molten 75 wt pct Na2SO4 25 wt pct K2SO4 was investigated at 900℃. The scale on the cast TiAlNb tends to spall in air, while the scale on coating is very adherent. The sputtered Ti-48Al-8Cr-2Ag coating remarkably improved high temperature oxidation resistance of the cast Ti-46.5Al-5Nb alloy because of the formation of an adherent Al2O3 scale. Due to the inward diffusion of Cr,Kirkendall voids were found at the coating/substrate interface. TiAlCrAg coating provided excellent hot corrosion resistance for TiAlNb alloy in molten 75 wt pct Na2SO4 25 wt pct K2SO4 at 900℃ due to the formation of a continuous Al2O3 scale.
Keywords:High temperature oxidation  TiAlCrAg coating  Hot-corrosion
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