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Fabrication of Shape-Controlled Au Nanoparticles in a TiO2-Containing Mesoporous Template Using UV Irradiation and Their Shape-Dependent Photocatalysis
作者姓名:T. Okuno  G. Kawamura  H. Muto  A. Matsuda
基金项目:supported by Grants-in-Aid for Young Scientists(Start-up)21860045;Young Scientists(B)22760539 from the Japan Society for the Promotion of Science(JSPS)
摘    要:A SiO_2-TiO_2 template with ordered tubular mesochannels has been prepared by the sol—gel method.Au nanorods are deposited in the tubular mesochannels of the SiO_2—TiO_2 template,and the shape of Au is changed from nanorods to nanospheres by ultraviolet irradiation during thermal deposition.The photocatalytic activity of mesoporous SiO_2—TiO_2 with/without Au nanorods/nanospheres is evaluated.Deposition of Au in the mesoporous SiO_2—TiO_2 template enhances the photocatalysis of TiO_2.Interestingly,the sample containing Au nanorods exhibits higher photocatalytic activity than that with Au nanospheres.Photocatalysis by exciting surface plasmon resonance is not detected in the composite samples regardless of the shape of the deposited Au nanoparticles.

关 键 词:介孔二氧化硅  光催化活性  纳米TiO2  紫外线照射  纳米粒子  模板  形状  表面等离子体激元
收稿时间:5 November 2012

Fabrication of Shape-Controlled Au Nanoparticles in a TiO2-Containing Mesoporous Template Using UV Irradiation and Their Shape-Dependent Photocatalysis
T. Okuno,G. Kawamura,H. Muto,A. Matsuda.Fabrication of Shape-Controlled Au Nanoparticles in a TiO2-Containing Mesoporous Template Using UV Irradiation and Their Shape-Dependent Photocatalysis[J].Journal of Materials Science & Technology,2014,30(1):8-12.
Authors:Teruhisa Okuno  Go Kawamura  Hiroyuki Muto  Atsunori Matsuda
Affiliation:[1]Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan [2]Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan
Abstract:Mesoporous Titania Gold Shape control Photocatalysis Surface plasmon resonance
Keywords:Mesoporous  Titania  Gold  Shape control  Photocatalysis  Surface plasmon resonance
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