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La_(0.60)Sr_(0.40-x)K_xMnO_3系列材料的磁电阻效应
引用本文:赵福伟,唐贵德.La_(0.60)Sr_(0.40-x)K_xMnO_3系列材料的磁电阻效应[J].材料科学与工程学报,2012,30(3):468-472.
作者姓名:赵福伟  唐贵德
作者单位:1. 河北工程技术高等专科学校,河北沧州,061001
2. 河北师范大学物理科学与信息工程学院,河北石家庄,050024
基金项目:河北省自然科学基金资助项目,河北省基础研究重点资助项目
摘    要:利用溶胶-凝胶法(sol-gel)制备了多晶类钙钛矿型稀土锰氧化物La0.60Sr0.40-xKxMnO3(x=0.00,0.15,0.20,0.30)。发现K+取代部分Sr2+后,可使样品的居里温度降至室温附近,并且使样品的室温磁电阻比替代前明显增大。在1.8T的磁场下,x=0.30的样品磁电阻峰值为21%,相应的峰值温度为304K。而母体La0.60Sr0.40MnO3的磁电阻峰值仅为6.4%,峰值温度为373K。可见K+离子替代使室温附近样品的庞磁电阻效应有了明显的改善。

关 键 词:钙钛矿锰氧化物  磁电阻  溶胶-凝胶法

Magnetoresistance of La0.60Sr0.40-xKxMnO3
ZHAO Fu-wei,TANG Gui-de.Magnetoresistance of La0.60Sr0.40-xKxMnO3[J].Journal of Materials Science and Engineering,2012,30(3):468-472.
Authors:ZHAO Fu-wei  TANG Gui-de
Affiliation:1.Hebei Engineering and Technical College,Cangzhou 061001,China; 2.College of Physics and Information Engineering,Hebei Normal University,Shijiazhuang 050024,China)
Abstract:Polycrystalline perovskite rare-earth manganites La0.60Sr0.40-xKxMnO3(x=0.00,0.15,0.20,0.30) were synthesized by sol-gel method.It is found that when Sr2+ ions are partly substituted by K+ ions,the Curie temperature of substituted samples can decrease to room temperature and the room temperature magnetoresistance(MR) increases obviously comparing with un-substituted La0.60Sr0.40MnO3.Under an applied filed of 1.8T,there is a maximum MR with 21% at 304 K for the sample La0.60Sr0.1K0.3MnO3.However,under the same applied field,there is only a maximum MR with 6.4% at 373 K for the un-substituted sample La0.60Sr0.40MnO3.Therefore,K+ ion substitution can remarkably improve the MR of this kind of material.
Keywords:perovskite manganite  magnetoresistance  sol-gel method
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