Preparation and structural properties of the solid state ionic conductor CuTi2 (PO4)3 |
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| Authors: | A Mbandza E Bordes P Courtine |
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| Affiliation: | Département de Génie Chimique, Université de Technologie de Compiègne B.P. 233, 60206 Compiègne Cédex, France |
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| Abstract: | The solid state ionic conductor CuTi2(PO4)3 belonging to the Nasicon family has been synthesized; its lattice parameters have been obtained from X-ray diffraction patterns by comparison with isostructural NaTi2(PO4)3. The characterization of this light brown solid has been completed by IR and UV-visible spectroscopies. Reverse ion exchange between Cu and Na has been shown to occur in a molten salt bath. These properties are discussed through the main structural features of the MIM′IV2(PO4)3 family. |
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