Effect of plasticizer on the electric-field-induced adhesion of dielectric PVC gels |
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Authors: | Mohammad Ali Toshihiro Hirai |
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Affiliation: | (1) Smart Materials Engineering, Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida Ueda, Nagano 386-8567, Japan; |
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Abstract: | Four different plasticizers have been used to make the PVC gels: poly(vinyl chloride)–diethyl adipate (PVC–DEA), poly(vinyl
chloride)–dibutyl sebacate (PVC–DBS), poly(vinyl chloride)–dioctyl phthalate (PVC–DOP) and poly(vinyl chloride)–dibutyl phthalate
(PVC–DBP). The chemical structure and molecular weight of the plasticizers significantly affected the electric-field-induced
adhesion of the gels. To explain the variations, the dielectric properties, space charge distributions, tensile properties
and Raman spectra of the PVC gels were compared. Aliphatic ester (DEA and DBS) plasticizer-containing PVC gels showed larger
electric-field-induced adhesion and dielectric constants than phthalate plasticizer (DBP and DOP)-containing gels. Raman spectroscopy
suggested that there were different molecular interactions between PVC and the plasticizers. The dielectric constant and mechanical
properties of the PVC gels were determined to be the key factors for determining the electric-field-induced adhesion. |
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Keywords: | |
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