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Solvothermal synthesis of hexagonal ZnO nanorods and their photoluminescence properties
Authors:Wei Dong Zhou  Yong Cai Zhang
Affiliation:a College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou City 225002, China
b Central Lab of Yangzhou University, Yangzhou University, Yangzhou City 225009, China
Abstract:Pure hexagonal ZnO nanorods were synthesized by low-temperature (90 °C) solvothermal treatment of zinc acetate in 40-80 wt.% hydrazine hydrate aqueous solutions. The products were characterized by means of powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electronic microscopy (TEM), selected area electron diffraction (SAED), and room temperature photoluminescence (RTPL) spectra. They show a strong UV emission at around 380 nm upon excitation at 360 nm using a Xe lamp at room temperature. The influence on the quality of the nanorods was investigated while the content of the solvent changed. The as-synthesized ZnO nanorods are promising materials for nanoscale optoelectronic devices due to their excellent UV emission properties.
Keywords:Crystal growth  Nanomaterials  Optical materials and properties  Semiconductors  X-ray techniques
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