Fracture behavior and environmental stress cracking resistance (ESCR) of HIPS/PE blends and the effect of compatibilization on their properties

Attempts have been made to study the fracture behavior and environmental stress cracking resistance (ESCR) of HIPS/PE blends. The effect of compatibilization on their properties was also studied. EWF tests were conducted to measure the essential specific work of fracture (w_e) and non-essential specific work of fracture (βw_p). The ESCR of the samples was investigated using a special modified tensile creep test under an aggressive environment (sunflower oil). It was found that EWF methodology could be applied to uncompatibilized and compatibilized HIPS/PE blends as well as HIPS. The essential specific work of fracture of compatibilized HIPS/PE blends was higher than uncompatibilized HIPS/PE blends and pure HIPS, while its non-essential work of fracture was higher than uncompatibilized blends and lower than pure HIPS. The results also showed that the ESCR of HIPS decreases with incorporation of PE, but an effective compatibilization of this blend increases its ESCR even higher than pure HIPS. The different properties of compatibilized and uncompatibilized blends and HIPS, in EWF and ESCR tests, were attributed to the different mechanisms of fracture in these materials. The different mechanisms of fracture were justified using morphological studies performed on fracture surfaces of each sample. SEM images showed that there is a reasonable correlation between mechanisms of fracture and microstructure of the samples.