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TiO2在微孔型活性炭纤维上的固载及其对苯酚的光催化降解
引用本文:员汝胜,郑经堂,关蓉波,刘以红.TiO2在微孔型活性炭纤维上的固载及其对苯酚的光催化降解[J].新型炭材料,2005,20(1):45-50.
作者姓名:员汝胜  郑经堂  关蓉波  刘以红
作者单位:1. 中国科学院山西煤炭化学研究所,炭材料重点实验室,山西,太原,030001;中国科学院,研究生院,北京,100039
2. 中国科学院山西煤炭化学研究所,炭材料重点实验室,山西,太原,030001;石油大学,重质油加工国家重点实验室,山东,东营,257061
3. 石油大学,重质油加工国家重点实验室,山东,东营,257061
摘    要:以环氧树脂作为TiO2与活性炭纤维(ACF)之间联结的前驱体,使TiO2粘附于纤维表面。后经氮气氛下400℃-580℃不同温度的煅烧处理,制得TiO2/ACF复合体。采用BET,SEM,XRD及UV—Vis光谱等手段对复合体的物理化学特性进行了表征。以水中苯酚为目标污染物考察了TiO2/ACF样品的光催化性能、结果表明,460℃煅烧品较其他样品对苯酚具有更好的去除能力。在其重复利用过程中,始终保持了高的光催化效率,直至第三次循环,其最终对苯酚的去除量仍与P25粉体相当。而且,牢固负载的TiO2更具实用性,易于从水中回收。

关 键 词:TiO2  活性炭纤维  苯酚  二氧化钛  光催化降解  有机污染物  水处理技术

Immobilization of TiO2 on microporous activated carbon fibers and their photodegradation performance for phenol
YUAN Ru-sheng,ZHENG Jing-tang,GUAN Rong-bo,LIU Yi-hong.Immobilization of TiO2 on microporous activated carbon fibers and their photodegradation performance for phenol[J].New Carbon Materials,2005,20(1):45-50.
Authors:YUAN Ru-sheng  ZHENG Jing-tang  GUAN Rong-bo  LIU Yi-hong
Affiliation:YUAN Ru-sheng~
Abstract:The immobilization of TiO2 on ACF (TiO2/ACF) was performed using epoxy resin as binder between TiO2 and ACF, followed by calcination properties of the resulting materials were characterized by BET, SEM, XRD and UV-Vis spectra. The photodegradation behavior of TiO2/ACF prepared was investigated in aqueous solution using phenol as a target pollutant. It removal efficiency. When used repeatedly, TiO2/ACF still presented high photocatalytic efficiency, and the phenol removal in the third cycle was almost the same as Degussa P25, mainly anatase. Moreover, TiO2 is tightly bound to ACF, and can be easily handled and recovered from water.
Keywords:Titanium dioxide  Activated carbon fibers  Photodegradation  Phenol
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